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The new emission regulations in Europe, EU 6 will promulgate more realistic driving conditions with more stringent HC, CO, NOx and particulate emissions. This legislation will also include the WLTP (Worldwide harmonized Light vehicles Test Procedure) cycle for CO2 measurements and a new requirement called “Real-Driving-Emissions” (RDE) as well. The RDE requirement is to ensure modern vehicles comply with the legislation under all conditions of normal driving. More robust aftertreatment solutions are needed to meet these new requirements. This work introduces an improved three-way catalyst (TWC) for gasoline engines for these new regulations. It is tested under static and dynamic conditions and on several engines and vehicles with various drive cycles. It offers better thermal stability combined with lower backpressure than former TWC generations.

The oil ash accumulation on modern three way catalyst (TWC) as well as its influence on catalyst deactivation is evaluated as a parameter of oil consumption, kind of oil additive compound and additive concentration. The oil ash accumulation is characterized by XRF and SEM/EDX in axial direction and into the washcoat depth of the catalyst. The deposition patterns of Ca, Mg, P and Zn are discussed. The catalytic activity of the vehicle and engine bench aged catalysts is measured by performing model gas tests and vehicle tests, respectively. The influence of oil ash accumulation on the lifetime emission behavior of the vehicle is discussed.