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Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

A new exhaust emission control system has been developed which complies with the world's most severe emission standard: CARB PZEV. Leaner combustion in cold condition was enabled and rapid warm-up of a close-coupled catalyst was realized by utilizing a newly developed Intake Air Control Valve (IACV) system and hyper-atomization fuel injector. In addition, the newly developed HC adsorbing type 3-way catalyst realized cold HC reduction at lower cost. For further reduction of the exhaust emission, the Variable Valve Timing-Intelligent (VVT-i) system was positively operated immediately after the cold start. By the suitable operation of Variable Valve Timing (VVT), the blow-back from the cylinder enhanced the fuel atomization and re-burning of remaining unburned hydrocarbons (HCs), and increased in-cylinder residual gas reduces NOx.