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An experimental study of the effects of partially-oxidized biodiesel fuel on the degradation of fresh fuel was performed. A blend of soybean oil fatty acid methyl esters (FAMEs) in petroleum diesel fuel (30% v:v biodiesel, B30) was aged under accelerated conditions (90°C with aeration). Aging conditions focused on three different degrees of initial oxidation: 1) reduced oxidation stability (Rancimat induction period, IP); 2) high peroxide values (PV); and 3) high total acid number (TAN). Aged B30 fuel was mixed with fresh B30 fuel at two concentrations (10% and 30% m:m) and degradation of the mixtures at the above aging conditions was monitored for IP, PV, TAN, and FAME composition. Greater content of aged fuel carryover (30% m:m) corresponded to stronger effects. Oxidation stability was most adversely affected by high peroxide concentration (Scenario 2), while peroxide content was most reduced for the high TAN scenario (Scenario 3).

Tools are now publicly available that can potentially help a company assess the impact of its water use and risks in relation to their global operations and supply chains. In this paper we describe a comparative analysis of two publicly available tools, specifically the WWF/DEG Water Risk Filter and the WBCSD Global Water Tool that are used to measure the water impact and risk indicators for industrial facilities. By analyzing the risk assessments calculated by these tools for different scenarios that include varying facilities from different industries, one can better gauge the similarities and differences between these water strategy tools. Several scenarios were evaluated using the water tools, and the results are compared and contrasted. As will be shown, the results can vary significantly.

Two oxygenated fuels were evaluated on a single-cylinder diesel engine and compared to three hydrocarbon diesel fuels. The oxygenated fuels included canola biodiesel (canola methyl esters, CME) and CME blended with dibutyl succinate (DBS), both of which are or have the potential to be bio-derived. DBS was added to improve the cold flow properties, but also reduced the cetane number and net heating value of the resulting blend. A 60-40 blend of the two (60% vol CME and 40% vol DBS) provided desirable cold flow benefits while staying above the U.S. minimum cetane number requirement. Contrary to prior vehicle test results and numerous literature reports, single-cylinder engine testing of both CME and the 60-40 blend showed no statistically discernable change in NOx emissions relative to diesel fuel, but only when constant intake oxygen was maintained.

Corrosion failures of aluminum air conditioner evaporator cores have been reported in regions where the climate is relatively warm and humid. Microbiologically-influenced corrosion [MIC] has been implicated in these failures. Application of surface-treatment chemicals may inhibit microbiological (bacterial) growth and/or attachment, thereby reducing the potential for MIC. In this study, two laboratory methods were developed to evaluate selected surface-treatment chemicals for their ability to inhibit bacterial growth and reduce bacterial attachment to treated surfaces. Using the developed methods, two controlled-atmosphere brazed aluminum core materials and three surface-treatment chemicals were evaluated. Neither of the untreated core materials was found to inhibit the growth of the bacteria tested.

The deionized water/ethylene glycol coolant used in the Ford Focus Fuel Cell Vehicle (FCV) requires very low conductivity (< 5 μS/cm) to avoid current leakage and short circuiting, presenting a unique water chemistry issue. The coolant's initially low conductivity increases as: 1) ions are released from system materials through leaching, degradation and/or corrosion, and 2) organic acids are produced by ethylene glycol degradation. Estimating the leaching potential of these ions is necessary for design and operation of fuel cell vehicles. An on-board mixed-bed, ion exchange resin filter is used to maintain low conductivity by removing leached or produced ions. Various candidate materials were evaluated for leaching potential by exposing them to coolant at the design operating temperature for several months and periodically analyzing the coolant for ions.