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Future emission standards will require further reduction of harmful gaseous emissions such as HC, CO and NOx as well as consideration for greenhouse gas emissions such as CO₂. Gasoline engines with lean combustion spray-guided direct fuel injection in conjunction with turbocharging have a very high potential for fuel savings. The main challenge for stratified lean GDI aftertreatment systems is the development of a catalyst system to fulfill the emission legislation requirements under low exhaust temperature operating conditions with efficient use of precious metals. In addition to the very stringent emission legislation another challenge for the introduction of lean gasoline engines in North America is the higher sulfur content of the fuel compared to Europe. In this paper exhaust gas aftertreatment requirements for stratified gasoline direct injection engines will be discussed and the latest advances in catalyst and system development will be shown.

While the market share for diesel engines for LD vehicles in Europe has grown continuously in the past years, the market share in North America is still negligible. Until now, it has been possible to fulfill the limits for nitrogen oxides (NOx) both in Europe and in North America by engine measures alone, without using an active NOx aftertreatment system. With the introduction of Tier II Bin 8 and Tier II Bin 5 emissions legislation in the US in 2007, most new diesel applications will now require NOx aftertreatment. One of the possible technologies for the reduction of nitrogen oxides in lean exhaust gas is the NOx storage catalyst which has become the generally-accepted choice for engines with gasoline direct injection systems and which is also utilized in the current diesel Bluetec I systems from Daimler. For heavier applications urea-SCR is the preferred technology to fulfill NOx legislation limits.

Diesel engines have a strong contribution to the CO2 reduction in Europe in the past years. To enable these C02 reduction potential to the US market Mercedes Benz developed the BLUETEC technology for light duty diesel engines. The BLUETEC technology contains an optimized diesel engine and combustion system, an aftertreatment system with DOC, DPF and an active SCR catalyst with AdBlue Dosing System and an enhanced ECU functionality and calibration. For fulfilling the world strongest emission limits of the US legislation there have to be solutions developed for the handling of AdBlue under cold climate below -11°C, managing the refilling event, and the onboard diagnostic. To ensure the emission stability over full useful life on high NOx conversions level, intensive testing of the catalyst technology had to be done. In addition there are self learning functionalities for adapting the dosing strategy to ensure the maximum NOx performance.

Automotive catalysts close coupled to gasoline engines operated under high load are frequently subjected to bed temperatures well above 950 °C. Upon deceleration engine fuel cut is usually applied for the sake of fuel economy, robustness and driveability. Even though catalyst inlet gas temperatures drop down immediately after fuel cut - catalyst bed temperatures may rise significantly. Sources for catalyst temperature rise upon deceleration with fuel cut are discussed in this contribution.

To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.