Search Results

Light absorbing components of aerosols, often called black carbon (BC), are emitted from combustion sources and are believed to play a considerable role in direct atmospheric radiative forcing by a number of climate scientists. In addition, it has been shown that BC is associated with adverse health effects in a number of epidemiological studies. Although the optical properties (both absorbing and scattering) of combustion aerosols are needed in order to accurately assess the impact of emissions on radiative forcing, many models use radiative properties of diesel particulate matter that were determined over two decades ago. In response to concerns of the human health impacts of particulate matter (PM), regulatory bodies around the world have significantly tightened PM emission limits for diesel engines. These requirements have resulted in considerable changes in engine technology requiring updated BC measurements from modern engines equipped with aftertreatment systems.

A comparative analysis was made on the emissions from a 2004 and a 2007 heavy-duty diesel engine to determine how new engine and emissions technologies have affected the chemical compounds found in the exhaust gases. Representative samples were collected from a source dilution sampling system and analyzed for both criteria and unregulated gaseous and particulate emissions. Results have shown that the 2007 regulations compliant engine and emissions technology not only reduced the specifically regulated exhaust pollutants, but also significantly reduced the majority of unregulated chemical species. It is believed that these reductions were achieved through the use of engine optimization, aftertreatment system integration, and ultra-low sulfur diesel fuel.

Diesel particulate filters are designed to reduce the mass emissions of diesel particulate matter and have been proven to be effective in this respect. Not much is known, however, about their effects on other unregulated chemical species. This study utilized source dilution sampling techniques to evaluate the effects of a catalyzed diesel particulate filter on a wide spectrum of chemical emissions from a heavy-duty diesel engine. The species analyzed included both criteria and unregulated compounds such as particulate matter (PM), carbon monoxide (CO), hydrocarbons (HC), inorganic ions, trace metallic compounds, elemental and organic carbon (EC and OC), polycyclic aromatic hydrocarbons (PAHs), and other organic compounds. Results showed a significant reduction for the emissions of PM mass, CO, HC, metals, EC, OC, and PAHs.

Fuel-borne catalysts (FBC) have demonstrated efficacy as an important strategy for integrated diesel emission control. The research summarized herein provides new methodologies for the characterization of engine-out speciated emissions. These analytical tools provide new insights on the mode of action and chemical forms of metal emissions arising from use of a platinum and cerium based commercial FBC, both with and without a catalyzed diesel particulate filter. Characterization efforts addressed metal solubility (water, methanol and dichloromethane) and particle size and charge of the target species in the water and solvent extracts. Platinum and cerium species were quantified using state-of-the-art high resolution plasma mass spectrometry. Liquid-chromatography-triple quad mass spectrometry techniques were developed to quantify potential parent Pt-FBC in the PM extracts. Speciation was examined for emissions from cold and warm engine cycles collected from an engine dynamometer.

Experimental tests were conducted to determine the sensitivity of Diesel particulate matter (PM) at a given engine operating condition using a single cylinder research engine at the University of Wisconsin Engine Research Center. Utilizing a full dilution tunnel with a second stage partial dilution tunnel, the PM emissions were characterized. Physical properties were measured with a variety of instruments including a Scanning Mobility Particle Sizer (SMPS), Tapered Element Oscillating Microbalance (TEOM) as well as traditional filter-based gravimetric measurements. Chemical composition was determined through the use of the Thermal/Optical Transmittance (TOT) Method, Ion Chromatography (IC) and Inductively Coupled Plasma - Optical Emission Spectroscopy (ICP/OES). Particulate mass emissions were shown to be on the order of 0.05 g/bhp-hr for the light load engine operating condition selected.

Current regulations stipulate acceptable levels of particulate emissions based on the mass collected on filters obtained by sampling in diluted exhaust. Although precise, this gives us only aggregated information. If in addition to the mass based measurements, detailed chemical analysis of the particulate matter (PM) is performed, additional subtle information about the combustion process can be revealed. This paper reports the results of detailed chemical analysis of trace metal in the PM emitted from a single cylinder heavy-duty diesel engine. The trace metal concentrations are used as an indicator of oil consumption. Two techniques were used to make the trace metal concentration measurements. PM was captured on filters and trace metals were quantified with an Inductively Coupled Plasma Mass Spectrometer (ICPMS), and also an Aerosol Time-of-Flight Mass Spectrometer (ATOFMS) was used to perform particle size and composition measurements in real time.

Significant amounts of particle-phase organic compounds are present in the exhaust of diesel vehicles. It is believed that some of these compounds have a greater impact on human health and the environment than other compounds. Therefore, it is of significant importance to speciate particle-phase organic compounds of diesel particulate matter (PM) to clarify the effects of PM on human health and the environment, and to understand the mechanisms of organic compounds formation in PM. A dilution source sampling system was incorporated into the exhaust measurement system of a single-cylinder heavy-duty direct-injection (D.I.) diesel engine. This system was designed specifically to collect fine organic aerosols from diesel exhaust. The detailed system is described in Kweon et al. [27].

A dilution source sampling system has been incorporated into the exhaust measurement system of a research single-cylinder diesel engine. To allow more detailed assessment of the individual chemical components of the diesel particulate matter (PM) the exhaust dilution system includes a residence time chamber (RTC) to allow for residence times of 30 to 60 seconds in the second stage of dilution before sampling. Samples are collected on a range of different filters where mass loading, elemental and organic carbon (ECOC), trace metals, sulfate ions (SO4), particle-phase organic compounds, and semi-volatile organic compounds are evaluated. In addition, particle size distributions have been determined using a scanning mobility particle sizer (SMPS). Results show that the chemical composition of the particulate matter is highly dependent on the engine operating conditions.