Search Results

Pure biodiesel fuel (B100) is typically made of fatty acid methyl esters (FAME). FAME has different physical properties as compared to mineral diesel such as higher surface tension, lower volatility and higher specific gravity. These differences lead to a larger droplet size and thus more wall impingement of the fuel during injection in the combustion chamber. This results in higher levels of fuel dilution as the oil is scraped down into the crankcase by the scraper ring. The lower volatility also makes biodiesel more difficult to evaporate once it enters the crankcase. For these reasons, levels of fuel dilution in biodiesel fueled engines are likely to be higher compared to mineral diesel fueled engines. When in-cylinder dosing is applied to raise the exhaust temperature required for the regeneration of Diesel Particulate Filters (DPF's), biodiesel dilution in the engine oil may be elevated to high levels.

Because of the rising costs of engine tests, bench testing is a necessity in engine oil development. Which bench test to use remains a problem. Recently, we have reported on the use of electrical contact resistance (ECR) coupled with a ball-on-disk tribometer to study the formation and the durability of antiwear films from binary additive mixtures. This paper extends the ECR study to fully formulated fresh oils run in both fired gasoline engines and the ECR bench test. X-ray Photoelectron Spectroscopy (XPS) analyses of used Sequence VE engine parts from highash fully formulated lubricants are shown and the relationship of ECR film formation to fired-engine test performance is discussed.