Search Results

Aerogels are nanoporous structures with physical characteristics that make them promising for use in automotive exhaust catalysis systems: highly porous with low densities (<0.1 g/mL) and high surface area per unit mass (>300 m2/g) - features that provide favorable characteristics for catalysis of gaseous pollutants. Ceramic aerogels are also highly thermally insulating (∼0.015 W/mK) and able to withstand high temperatures. Aerogels can be made of a wide variety of ceramics (e.g. alumina, silica, titania) with other catalytically active metals (e.g. copper, cobalt, nickel) incorporated into their structures. This paper provides a brief overview of the rapid supercritical extraction (RSCE) method employed in this work for aerogel preparation, describes in detail the benchtop scale testbed and methods used to assess the catalytic activity of RSCE fabricated aerogels, and presents data on the catalytic ability of some promising aerogel chemistries.

The effects of reduced fuel injection pressure on the cold start performance of a GDI engine have been studied in a single-cylinder, optically-accessible research engine. Two Delphi Automotive Systems DI-G injectors, with included spray cone angles of 60° and 80° respectively, were studied. Both injectors are designed to operate at a nominal fuel line pressure of 10 MPa. For the study they were operated at several fuel feed pressures between 10 MPa and 2 MPa. Two start of injection timings (50° and 100° ATDC) were examined. Cold start performance was characterized by measurements of the GIMEP, COV of GIMEP, and total engine out UHCs. Simultaneous Planar Laser Induced Fluorescence (PLIF) and Mie Scattering images of the fuel spray were used to observe spray penetration, mixing, and in-cylinder fuel distribution throughout the intake and compression strokes. Ultimately these images were used to explain observed performance differences.

Experiments have been conducted in a laminar flow system and in a research engine to investigate the effect of additives on the combustion of gasoline-like fuels. The purpose of the laminar system is to enable rapid screening of additives to determine which, if any, have an enhancing effect on the early stages of combustion, especially under conditions of poor fuel vaporization which exist during cold-start in a spark ignited engine and which make flame propagation difficult to start and sustain. The base fuel used in the laminar and engine systems was a 9 component mixture formulated to simulate those components of gasoline expected to be present in the vapor phase in the intake system of an engine under cold-start conditions. In the laminar system, the pre-mixed, pre-vaporized fuel-air mixture is ignited and a time history of the combustion generated, hydroxyl radical chemiluminescence is recorded.

Results are presented from an experimental study of the effects of engine speed and injection pressure transients on the cold start performance of a gasoline direct injection engine operating on iso-octane. The experiments are performed in an optically-accessible single-cylinder research engine modified for gasoline direct injection operation. In order to isolate the effects of the engine speed and injection pressure transients, three different cold start simulations are used. In the first cold start simulation the engine speed and injection pressure are constant. In the second cold start simulation the injection pressure is constant while the engine speed transient of an actual cold start is simulated. In the third cold start simulation both the engine speed and the injection pressure transients of an actual cold start are simulated.

A Laser Induced Fluorescence (LIF) based technique has been employed to examine the transient fuel film behavior on an intake valve during cold start of a PFI engine. Fluorescence from a tracer in the fuel was collected through a Borescope and imaged onto a CCD camera, providing a 2-D image of the fuel film on the valve. The average intensity of the fluorescence, over a Region of Interest (ROI), was taken to be proportional to the total amount of fuel present in the film. Images were collected (at a fixed crank angle) on every second engine cycle, resolving changes in the fuel film during the cold start transient. Changes in the fuel film were resolved within a cycle by collecting images at varying crank angles during successive experiments. Results from four fuel mixtures are reported. Two simulated “single component fuels” one with a higher volatility (HV) and one with a lower volatility (LV), were examined.