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The use of portable emissions measurement systems (PEMS) for testing vehicle emissions while driving on the road has been demonstrated as early as the 1980s. Many users have taken the driving route and repeated the route in a chassis cell with the same vehicle expecting identical results. Emission results can be comparable but there are many factors that need to be considered. This study compares PEMS results for a driving route repeated across seasons and traffic conditions with a single vehicle. The ambient temperature variability and traffic is shown to cause variation in emissions for any individual run. Generating a test cycle to mimic the driving route can be done in a variety of ways. The simplest is to take an individual driving run and translate the time and speed trace directly. This does not address the statistical results from numerous driving runs on the same route.

Direct measurement of dilution air volume in a Constant Volume emission sampling system may be used to calculate tailpipe exhaust volume, and the total dilution ratio in the CVS. A Remote Mixing Tee (RMT) often includes a subsonic venturi (SSV) flowmeter in series with the dilution air duct. The venturi meter results in a flow restriction and significant pressure drop in the dilution air pipe. An ultrasonic flow meter for a similar dilution air volume offers little flow restriction and negligible pressure drop in the air duct. In this investigation, an ultrasonic flow meter (UFM) replaces the subsonic venturi in a Remote Mixing Tee. The measurement uncertainty and accuracy of the UFM is determined by comparing the real time flow rates and integrated total dilution air volume from the UFM and the dilution air SSV in the RMT. Vehicle tests include FTP and NEDC test cycles with a 3.8L V6 reference vehicle.

In the engine and vehicle test procedures described in Parts 1065/1066 of Title 40 of the Code of Federal Regulations (CFR), the United States Environmental Protection Agency (US-EPA) allows for the measurement of N2O emissions from sample storage bags, from a continuous dilute stream or a raw exhaust stream. Typically, batch (Bag) sampling has better accuracy and repeatability, but continuous sampling is more efficient in terms of test cell running time and provides test-mode emissions with good correlation to bag measurements. In this study, correlations between bag sampling and continuous dilute exhaust sampling were investigated using a fleet of vehicles with a wide range of N2O emission levels. Very good correlation between these two sampling methods was observed for the majority of tests conducted. In the best cases, differences in average N2O concentration levels measured by these two methods were less than +/− 1%.

This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

Engine testing in the United States has been updated with the new centralized testing procedure in 40 CFR 1065. This regulation introduces a variety of new checks and tests required for certification testing. Upgrading existing equipment to run these tests in some cases introduces error or does not follow the spirit of the regulation. The term “good engineering practice” is used within the regulation to insure users make decisions on differences or unclear implementation. This paper addresses some of the recommended modifications and evaluates the differences in the results with and without the modifications.

An on-board diesel particulate measurement (OBS-TRPM) instrument is developed to measure on-road exhaust PM emission at Horiba. It is used to characterize particulate matter (PM) emission from a gasoline vehicle, the 1999 Ford Windstar with California Ultra Low Emission (ULEV) certification. PM emissions from three test cycles, EPA FTP 72, SFTP-US06, and new European drive cycle (NEDC), are evaluated. It is found that the PM emission from the SFTP-US06 with the cold start is roughly two times higher than PM emissions from the cold FTP 72 and the cold NEDC. This may be due to aggressive drive patterns for the US06 while the vehicle is still cold. The aggressive drive pattern for the US06 makes the gasoline vehicle emit a much higher fraction of elemental carbon (EC), and lower fraction of organic carbon (OC). Fractions of the EC from the vehicle are 9.1% for the FTP 72, 6.3% for the NEDC, and 56.6% for the US06.

Monodisperse and polydisperse Sodium Chloride (NaCl) particles were used to calibrate the solid particle penetration for the Volatile Particle Remover (VPR) in a Horiba prototype Solid Particle Counting System (SPCS). Prior to the calibration, dilution ratios on the SPCS are verified carefully with a flame ionization analyzer (FIA). Size distributions for polydisperse aerosols upstream and downstream of the Volatile Particle Remover (VPR) were measured with a Scanning Mobility Particle Sizer (SMPS). It is found that overall penetrations for polydisperse aerosols are larger than 95%. Geometric standard deviations from the raw and the diluted by the VPR are within ±1.5% difference. Thus, shapes of size distributions aren't changed after dilution. Geometric mean diameters shift a little, on average ±5% after dilution. Therefore, the VPR doesn't change the aerosol characteristics after the aerosol is diluted and heated up to 320 °C.

On-board measurement is a powerful method to assess vehicular exhaust gas emission, since it enables the acquisition of instantaneous raw emission values in real-world conditions. While the vehicle emissions are subject to traffic and environment fluctuations, on-board measurement is a fast and economical way to generate data for fleet emission inventories, for instance. It is part of the mandatory testing for heavy-duty vehicles in the USA, as regulated by the USEPA. In 2004, Petrobras (Brazilian Oil Company) first experienced on-board emission measurements while participating in an international joint project, whose objective was to obtain information regarding the light-duty vehicular gas emission contribution to pollutant levels in some of the major Latin-American cities.

A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.

In response to the appearance of formal regulations, CFR part 1065 subpart J, a new in-use emission measurement system was developed, the OBS 2000. The OBS 2200 uses partial-vacuum analyzers. The heated flame ionization detector (HFID), heated chemiluminescence detector (HCLD) and heated non-dispersive infrared analyzer (HNDIR) are all upstream of the sample pump. This design decreases the response time of the analyzers, lowers power consumption and minimizes the overall dimensions of the system by avoiding the use of a heated sample pump. The size of the heated zones is also minimized to reduce power usage. Typical power consumption of analyzer unit is less than 500 W. The overall dimension of the main unit is 350mm (W) × 330mm (H) × 500mm (D). Analyzer linearity checks as required by new regulations [1] for all available ranges will be presented along with cut point accuracies relative to full scale and percentage of point.

Recent papers have investigated the influence of sample composition on Flame Ionization Detector (FID) instrumentation used to measure total hydrocarbon content in exhaust emission samples. In this paper we describe experiments and results that further define these effects. Specially blended propane in air cylinders were crafted to provide a nominal 3 ppmC propane concentration with an oxygen content ranging from 17.5 vol % to 21 vol%. These cylinders were evaluated on multiple FID designs and then used to evaluate a strategy to correct the effects of the interaction. The study shows that, in general, most FID's behave similarly in response to changing oxygen content in the presence of hydrocarbon. Anomalies are discussed. The cylinders are then used to demonstrate that a proposed method for correcting the oxygen and hydrocarbon interaction is successful in reducing the effects.

The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.

The regulated level of particulate mass for 2007 heavy duty diesel on-road engines is 0.01 g/bkhp-hr. Measurement of this low level of particulate by weighing is costly and time consuming. The weighing method must measure 100 μg or less of particulate on a filter that weighs about 100 mg with a resolution of ± 2.5 μg or better. This means that the microbalance and sampling handling procedure must be accurate within ±25 ppm by mass or ±1/40,000. It requires a microbalance with 0.1 μg precision housed in a special environment. Moreover, the weighing method involves a lengthy process. The filter must be equilibrated, and then pre- and post-weighed, usually with repeat measurements. An alternative to gravimetric analysis is a thermal mass analyzer that measures the semi-volatile organic fraction (SOF), as well as soot and sulfate fractions of the particulate matter (PM) collected on a cleaned quartz filter. The calibration of the thermal mass measurement is discussed in detail.

Automotive emissions have been regulated to very low mass emissions. Various collection techniques have been utilized to measure the emitted gases. Some sample collection techniques utilize dilution gases that have concentrations below ambient air background values. For these applications analyzers with very low ranges have been produced. When using analyzers with ranges below 10 ppm, gas accuracy and impurities become very critical to the successful operation of these analyzers. A general demonstration of analyzer accuracy will be presented for various ranges. The availability and accuracy of the reference gases will be discussed. The relationship between the accuracy of the gas labeling and the analyzer's calibration accuracy will be evaluated. Gas delivery components can also affect the purity of zero gases and the accuracy of gas mixtures. Oxygen cleaned gas cylinder regulators will be compared to standard regulators for THC background contribution.

With the need for emission measurements of super ultra low emission vehicles (SULEV), analyzer manufacturers have been required to produce more precise and accurate analyzers. In order to compare analyzers, the customer must understand the different specifications used by the analyzer manufacturers. One specification that some manufacturers have used is the limit of detection (LOD) to indicate the reliability of the analyzer output at low concentrations. There are various methods for determining the LOD for a given analyzer. The authors will demonstrate how variations in methodology can produce different LOD values for a specific analyzer and what it means for the automotive emission analyzers. It is also demonstrated that the standard deviations of a zero signal, which is related to LOD, can be heavily influenced by data processing, such as data length in use and/or data smoothing. The LOD values obtained will be compared to the limit of quantification (LOQ) for that analyzer.