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Synthetic diesel fuels from Fischer-Tropsch or hydrotreating processes have high cetane numbers with respect to conventional diesel fuel. This study investigates diesel combustion characteristics with these high cetane fuels. A military jet fuel (JP-5 specification), a Fischer-Tropsch (FT) synthetic diesel, and normal hexadecane (C16), a pure component fuel with defined cetane number of 100, are compared with operation of conventional military diesel fuel (F-76 specification). The fuels are tested in a AM General GEP HMMWV engine, an indirect-injection, largely mechanically-controlled diesel engine. Hundreds of thousands of these are in current use and are projected to be in service for many years to come. Experimental testing showed that satisfactory operation could be achieved across the speed-load operating map even for the highest cetane fuel (normal hexadecane). The JP-5, FT, and C16 fuels all showed later injection timing.

Future synthetic diesel fuels will likely involve mixtures of straight and branched alkanes, possibly with aromatic additives to improve lubricity and durability. To simulate these future fuels, this study examined the combustion characteristics of binary mixtures of 50%, 70%, and 90% isododecane in hexadecane, and of 50%, 70%, and 80% toluene in hexadecane using a single-cylinder research diesel engine with variable injection timing. These binary blends were also compared to operation with commercial petroleum diesel fuel, military petroleum jet fuel, and five current synthetic Fischer-Tropsch diesel and jet fuels. The synthetic diesel and jet fuels showed reasonable similarity with many of the combustion metrics to mid-range blends of isododecane in hexadecane. Stable diesel combustion was possible even with the 80% toluene and 90% isododecane blends; in fact, operation with 100% isododecane was achieved, although with significantly advanced injection timing.

This study considers the relatively high fuel consumption of small-displacement Diesel engines and seeks to improve it through thin ceramic thermal barrier coatings. A small displacement (219 cc) single-cylinder direct-injection production Diesel engine is utilized. A Ricardo WAVE simulation is developed and suggests that through simultaneous application of the coatings and reduction of compression ratio, the fuel consumption can be improved through a reduction in thermal losses. At the stock compression ratio, the application of thermal barrier coatings does not improve fuel consumption unless injection timing is carefully controlled. When injection timing is also adjusted, fuel consumption can be improved by up to 10%, particularly at low loads, with application of the thermal barrier coatings. The data show higher rates of energy release, higher peak pressures, leading to the lower fuel consumption.

Fast emissions analysis, soot analysis, and pressure sensing is utilized to examine the first few seconds before, and after startup in a single-cylinder CFR diesel engine. The equivalence ratio, compression ratio, and injection timing are varied. The data show that UHC and CO emissions are highest at the highest and lowest fueling conditions, while NOx emissions peaked at intermediate fueling conditions. Leaner operating conditions show delayed starting but reduced ignition delay. Oil vapor causes soot emissions prior to first combustion, and soot particle size shifts higher during the first few seconds after combustion begins. Injection timing has little effect except at the leanest equivalence ratios, where a retarded injection timing increases the delay until a successful combustion event. At lower compression ratios, large IMEP oscillations occurred during startup. The data suggest possible strategies to optimize diesel startup.

Fischer-Tropsch (FT) synthetic fuels have been shown to produce lower soot and oxides of nitrogen emissions than petroleum-based diesel #2 (D2) in previous studies. This performance is frequently attributed to the very low aromatic content as well as essentially zero sulfur content. The objective of this empirical study was to investigate the high engine load regime using a military FT and D2 fuel in a CFR diesel engine at fueling levels approaching stoichiometric. A testing matrix comprised of various injection advance set points, fueling amounts (e.g. load) above 6 bar gross indicated mean effective pressure (IMEPg), and three different compression ratios (CR) was pursued. The results show that oxides of nitrogen emissions are always equal to or lower running FT compared to diesel. This result is attributed to the higher cetane number of FT leading to lower peak in-cylinder pressures as compared to D2.

Ethanol based fuels have seen increased use in recent years due to their renewable nature as well as increased governmental regulatory mandates. While offering performance advantages over gasoline, especially at high compression ratios, these fuels are more sensitive to pre-ignition (PI). Pre-ignition experiments using ethanol (E100) and E85 were performed in a CFR spark ignition engine using a diesel glow plug “hot spot” to induce PI. PI is found to occur over a specific air-fuel ratio range based on hot spot temperature. Additionally, increasing ethanol content or compression ratio (CR) decreases glow plug temperature thresholds for PI. A kinetics-based model was used to simulate pre-ignition of E100 and to elucidate sensitivities of pre-ignition to various operating parameters, including initial charge temperature, air dilution, and residual dilution. The model shows that the most violent cases of PI can be mitigated by switching to either lean or rich operation.

Seven biofuel-diesel fuel configurations were tested in a single-cylinder research diesel CFR engine that allowed variable injection timing. These seven configurations included three biodiesel-diesel blends (20% and 100%); two ethanol-diesel blends (15% and 20%), and two cases in which ethanol was injected into the intake air flow (20% and 33%). Combustion characteristics, NOx emissions, and soot emissions were compared with diesel operation across a range of injection timings. The effect of fuel compressibility affected the timing of injection, with biodiesel-diesel blends having advanced injection and ethanol-diesel blends having delayed injection. Biodiesel-diesel blends showed reduced ignition delay with only modest changes in combustion duration, while ethanol-diesel mixtures showed longer ignition delay but much shorter combustion duration and earlier phasing.

In the near future increasing use of ethanol in motor fuels will occur due to legislative mandates. E10 (Gasohol) and E85 will see more widespread use in spark ignition engines. This study looks at the performance and knock characteristics of E10 and E85 in comparison to regular gasoline. Detailed experimental engine data and analysis as a function of compression ratio, ignition timing and fueling are presented with associated physical explanations. Comparative results are presented. Increasing ethanol content provides for greater engine torque, efficiency and knock tolerance, yet fuel consumption worsens. Knock limited trends and sensitivities are presented, for example, 5 degrees of spark retard are required with E10 and gasoline for each compression ratio increase, while the much less sensitive E85 requires only 2 degrees of retard for each compression ratio increase. Trends with efficiency and torque are described amongst the fuels tested.

Internal combustion engine knock has limited compression ratios of spark ignition engines for most of the history of gasoline engines. This limitation continues to exist today. While knock is generally a low engine speed, high load phenomenon, this operating condition is infrequently used by many vehicle operators, and if the engine is brought to this operating condition generally little time is spent in this knock prone condition. This study seeks to investigate the transition into knock due to throttle changes from part to full load. The experimental results using a CFR engine operating on iso-octane fuel show that knock is delayed by at least one high load engine cycle after the throttle is opened. Optimization of spark timing to account for this effect provides for the best increase of engine load without audible knock occurring.

Residual-effected HCCI is investigated using a single-cylinder research engine equipped with fully-flexible variable valve actuation. Dilution limits are explored with various valve profiles in order to gain insight into the best way to use exhaust residual to achieve and control HCCI. The tests repeatedly point out the importance of delayed combustion phasing to reduce thermal losses and maximize efficiency. Combustion phasing is not significantly affected by charge in-cylinder residence time, but is strongly influenced by both the level of exhaust residual and by valve strategies that aim to affect homogeneity. Further dilution with air shows little promise for reaching lower loads, but does suggest that operation near the lean limit can maximize efficiency while minimizing NO and CO emissions.

Studies have been conducted to assess the potential of variable valve actuation to initiate homogeneous charge compression ignition (HCCI) through reinduction of exhaust from the previous combustion cycle. As opposed to strategies which induce HCCI through use of either intake or exhaust throttling, use of exhaust reinduction incurs no pumping penalty, making it particularly attractive as a method for achieving efficient, light-load combustion. Using a fully flexible electrohydraulic valve actuation system, tests were conducted on a single-cylinder research engine using three strategies: late exhaust valve closing, late intake valve opening (used in conjunction with the exhaust valve being left open throughout the intake stroke), and a combination of the two. Results show that IMEP values from ∼30-55% of unthrottled SI combustion output could be obtained by varying the valve timings used to implement reinduction.