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The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

Engines using natural gas as their main fuel are attracting attention for their environmental protection and energy-saving potential. There is demand for improvement in the thermal efficiency of engines as an energy-saving measure, and research in this area is being actively pursued on spark ignition engines and HCCI engines. In spark ignition gas engines, improving combustion under lean condition and EGR (exhaust gas recirculation) condition is an issue, and many large gas engines use a pre-chamber. The use of the pre-chamber approach allows stable combustion of lean gas mixtures at high charging pressure, and the reduction of NOx emissions. In small gas engines, engine structure prevents the installation of pre-chambers with adequate volume, and it is therefore unlikely that the full benefits of the pre-chamber approach will be derived.

Recently, a potentiality of Dedicated EGR (D-EGR) concept SI engine has been studied. This concept engine had four cylinders and operated with exhaust gas supplied from the single cylinder to the intake manifold. Compared with conventional SI engines, it was able to increase thermal efficiency and decrease CO, HC, and NOx emission by the high D-EGR ratio 0.25. In this study, numerical analysis of a SI engine with D-EGR system with various D-EGR ratios was conducted for detailed understanding the potentiality of this concept in terms of thermal efficiency and NOx emission. #1 cylinder of assumed engine was used as D-EGR cylinder that equivalence ratio varied from 0.6 to 3.4. Entire exhaust gas from #1 cylinder was recirculated to the other cylinders. The other cylinders run with this exhaust gas and new premixed air and fuel with various equivalence ratios from 0.6-1.0.

A fuel design concept for an HCCI engine based on chemical kinetics to optimize the heat release profile and achieve robust ignition was proposed, and applied to the design of the optimal methane-based blend. Ignition process chemistry of each single-component of natural gas, methane, ethane, propane, n-butane and isobutane, was analyzed using detailed chemical kinetic computations. Ethane exhibits low ignitability, close to that of methane, when the initial temperature is below 800 K, but higher ignitability, close to those of propane, n-butane and isobutane, when the initial temperature is above 1100 K. Furthermore, ethane shows a higher heat release rate during the late stage of the ignition process. If the early stage of an ignition process takes place during the compression stroke, this kind of heat release profile is desirable in an HCCI engine to reduce cycle-to-cycle variation during the expansion stroke.

The ignition delay times and heat release profiles of CH4, C2H6, C3H8, i-C4H10, and n-C4H10 and dual-component CH4-based blends with these alkanes in air were determined using a detailed chemical kinetic model. The apparent activation energy of C2H6 in the relationship between initial temperature and ignition delay time is higher than those of the other alkanes because OH formation is dominated by H2O2(+M)=OH+OH(+M) from the beginning over a wide range of initial temperatures. The heat release rate of C2H6 is higher than those of the other alkanes in the late stage of ignition delay time because H2O2 is accumulated with a higher concentration and promotes the OH formation rate of H2O2(+M)=OH+OH(+M). These ignition characteristics are reflected in those of CH4/C2H6.

Recently, producing energy with reduced CO₂ emissions has been one of the most important topics of global discussion. Combined heat and power (CHP) systems, which use natural gas to produce thermal energy and electric energy simultaneously, are considered to contribute significantly to the efficient use of energy and environmental conservation. The prevalence of CHP systems is expected. From an energy security point of view, promoting the introduction of distributed energy systems, which use natural gas, is highly recommended. In a CHP natural gas engine, enhancing engine efficiency is required to save energy. The challenge with spark ignition (SI) engines is how to improve destabilizing firing in the situation of a mixed lean burn and exhaust gas recirculation (EGR) condition. This is especially important in large size of lean combustion natural gas engines, which use a pre-chamber to maintain spark ignition performance, while also avoiding knocking.

Small two stroke SI engines supplied with natural gas in the intake port are advantageous for low maintenance and low cost when used in co-generation systems for residential use. However in the engines with port injection systems, the unburned HC emissions are higher and thermal efficiency is lower than with 4 stroke engines. To overcome these disadvantages, an in-cylinder injection with a special low pressure injection nozzle system was attempted. The results showed that improvements in unburned HC emissions and thermal efficiency are possible due to the remarkable reduction in scavenging loss and the lean combustion.