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In order to study the influence of lubricant ash on the performance of the CN6 after-treatment system, especially the catalyst characteristics of Coated Gasoline Particulate Filter (CGPF), the system was rapidly aged on the engine bench by blending combustion method, and the ash content of 60g represented the endurance of 200kkm CGPF. The effects of CGPF with different endurance mileage on particulate matter emission, gas light-off temperature and engine performance of a Gasoline Direct Injection (GDI) vehicle were studied on the engine bench, chassis dynamometer and real-road tests. Finally, the ash distribution was analyzed by computed tomography (CT). The results showed that the vehicle equipped with CGPF could meet the requirements of CN6 particulate and gas emission limits under both worldwide harmonized light vehicles test cycle (WLTC) and real driving emission (RDE) tests.

Future NOx-emission standards for diesel engines imply an after treatment system, e.g. in the form of an NH3-SCR system. For the technical realization a sound understanding of the catalytic processes is mandatory. To gain this knowledge a model of the SCR of NO with NH3 on Fe zeolite catalysts has been developed on the basis of a transient test cycle. The model is able to map the performance of the catalyst both under steady state and transient conditions. As practical examples the model is used to parameterize lookup tables and to compare different formats of lookup tables in terms of suitability for a urea dosage system.

The present work intends to examine the selective NOx reduction efficiency of a current commercial Titanium-Vanadium washcoated catalyst and to develop a transient numerical model capable of describing the SCR process while using a wide range of inlet conditions such as space velocity, oxygen concentrations, water concentration and NO2/NO ratio. The concentrations of different components (NO, NO2, N2O, NH3, H2O and HNO3) were analyzed continuously by a FT-IR spectrometer. A temperature range from 150°C up to 650°C was examined and tests were carried out using a model exhaust gas comparable to the real diesel exhaust gas composition. There is a very good correlation between experimental and calculated results with the given chemical kinetics.

Future three way catalyst systems are expected to consist of a relatively small start catalyst and a larger volume underfloor catalyst. The main role of the start catalyst is to provide rapid light off. For this purpose, the start catalyst requires relatively small volume with high precious metal loading. Computer simulation is employed to optimize the start catalyst volume with respect to light off performance and precious metal cost. The main role of the underfloor catalyst is NOx removal at elevated temperatures and high space velocities. Due to its large volume, substantial precious metal savings can be realized by the design of a low precious metal underfloor catalyst. The present study focuses on a systematic understanding of NOx breakthrough in three-way catalysts. Special emphasis is on the interaction of the catalyst and the engine management system, especially the lambda control.

The LEV II and EURO V legislation in 2007/2008 require a high conversion level for nitrogen oxides to meet the emission levels for diesel SUVs and trucks. Therefore, U.S. and European truck manufacturers are considering the introduction of urea SCR systems no later than model year 2005. The current SCR catalysts are based mainly on systems derived from stationary power plant applications. Therefore, improved washcoat based monolith catalysts were developed using standard types of formulations. These catalysts achieved high conversion levels similar to extruded systems in passenger car and truck test cycles. However, to meet further tightening of standards, a new class of catalysts was developed. These advanced type of catalytic coatings proved to be equivalent or even better than standard washcoat formulations. Results will be shown from ESC, MVEG and US-FTP 75 tests to illustrate the progress in catalyst design for urea SCR.

It is well known that the catalytic efficiency and durability of an automotive catalytic converter can be significantly affected by its design. This paper demonstrates the potential for further improvement in both the durability and efficiency by using a novel catalytic converter concept based on a large frontal area, high cell density substrate. This concept requires that attention be paid to optimization of the flow as well as of the mounting system. The converter design is determined with a computational fluid dynamic (CFD) simulation and the effect of this design on the temperature distribution in the substrate is calculated and measured. Due to this novel converter concept the maximum substrate temperature is reduced, which results in a better aging behavior. This improvement allows a reduction in precious metal content without a loss in efficiency.

This paper will discuss a number of different matters relating to the regeneration of catalyst coated diesel particulate filters such as: impact of the catalyst on the soot ignition temperature, soot combustion rate and NO2 generation. If catalytic coatings prove to be sufficient compared to certain fuel additives they could be used in second generation diesel particulate aftertreatment systems. Examples will be shown on how catalytic diesel particulate filters (“DPF”) can operate on a common rail passenger car diesel engine. Furthermore, an outlook is given on the future combination of particulate - and NOx - emission control for diesel passenger cars.

This paper describes the function and application of the preoxidation, hydrolysis and SCR catalysts individually and as a combined system for urea SCR both in model gas and engine bench tests. Using the basic system and a non-optimized urea injection strategy 45% NOx conversion was achieved in the ESC engine test. Adding a preoxidation catalyst significantly improved the NOx conversion in the low temperature region of the engine mapping. NOx conversions over 75% can be achieved in the ESC test using this improved system. With a 50% reduced SCR catalyst volume still a NOx conversion of over 65% could be achieved. Tests after 200 hours engine aging show that the activity of the system is stable.