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Internal combustion engine (ICE) cold-start is an issue that occurs either in conventional and hybrid powertrains before the ICE reaches its normal operation temperature, affecting both fuel consumption due to higher heat losses, and pollutant emissions due to low catalytic converter temperatures. The study of cold start emissions on conventional powertrains has been extensively addressed, although typically under laboratorial conditions, however studies addressing the impact of this phenomenon on hybrid powertrains is still reduced. Hybrid electric (HEV) and plug-in hybrid electric (PHEV) vehicles usually incorporate technologies to manage the battery and ICE power supply leading to ICE on/off operation under regular driving, which can result in a decrease on catalytic converter efficiency (due to cooling).