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This research involved studying the effects of adding small amounts of hydrogen or hydrogen and oxygen to a gasoline fuelled spark ignition (SI) engine at part load. The hydrogen and oxygen were added in a ratio of 2:1, mimicking the addition of water electrolysis products. It was found that the effects of hydrogen addition (≈ 2.8% of the fuel by mass, ≈ 60% by volume) decreased as the fuel/air equivalence ratio approached ϕ = 1. When operating at ϕ ≤ 0.8, the torque, indicated mean effective pressure (imep) and NO emissions increased and cycle-to-cycle variation decreased with hydrogen addition. The improvements in engine performance and increase in NO emissions were related to a faster burn rate shown by a decrease in burn duration with the addition of hydrogen. Further, the addition of hydrogen only and hydrogen and oxygen in a ratio of 2:1 were compared. The extra oxygen had little effect on engine performance other than an increase in NO exhaust concentration ∼ 500 ppm.

The effects of the addition of small amounts of molecular and atomic hydrogen/oxygen on laminar burning velocity, pollutant concentrations, and adiabatic flame temperatures of premixed, laminar, freely propagating iso-octane flames are investigated using CHEMKIN kinetic simulation package and a chemical kinetic mechanism at different equivalence ratios. It is shown that hydrogen/oxygen additives increase the laminar burning velocities. Increased hydroxyl (OH) concentrations resulted in reduced carbon monoxide (CO) emissions in every stoichiometric ratios investigated. Additives also increased the adiabatic flame temperature of iso-octane/air combustion, thereby causing increased NOx concentrations for all additives at all stoichiometries.

A semi-empirical turbulent flame growth model has been developed based on thermodynamic equilibrium calculations and experiments in a 125-mm cubical combustion chamber. It covers the main flame growth period from spark kernel formation until flame wall contact, including the effects of laminar flame speed, root mean square turbulence intensity, turbulent eddy size, and flame size. As expected, the combustion rate increases with increasing laminar flame speed and/or turbulence intensity. The effect of turbulent eddy scale is less obvious. For a given turbulence intensity, smaller scales produce higher instantaneous flame speed. However, turbulence of a smaller scale also decays more rapidly. Thus, for a given laminar flame speed and turbulence intensity at the time of ignition, there is an optimum turbulent eddy size which leads to the fastest combustion rate over the period considered.