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One of most effective NOx control technology of modern diesel engines is SCR with ammonia. Current NOx reduction systems are designed to use a solution of urea dissolved in water as a source of ammonia. However, the liquid urea systems have technical difficulties, such as a freezing point below −11°C and solid deposit formation in the exhaust temperature below 200°C. The objective of this study is to investigate the possibility of a new ammonia generation system that uses low-cost solid ammonium salt, such as solid urea and ammonium carbonate. The result shows that ammonium carbonate is more suitable than solid urea because of low decomposition temperature and no change to the other ammonium salt during the decomposition process. This paper also shows the NOx reduction capability of the new ammonia delivery system that uses ammonium carbonate.

In the present study, a bench-flow reactor is used to perform lean/rich thermal cycling on model “Ba+K” LNT catalysts at temperatures of 700, 800, 900 and 1000°C using simulated diesel exhaust gases. Deterioration of NOx performance is measured and the deactivation mechanisms of thermally-aged “Ba+K” LNTs are identified using characterization techniques such as TEM, XRD and EPMA. Results indicate that the deterioration is minimal at 700 and 800°C, however, at aging temperatures exceeding 800°C the severity of thermal aging depends on aging temperature as well as number of aging cycles.