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An evaluation methodology has been developed for assessing the suitability of R-1234yf in vehicles. This relates primarily to evaluating the flammability of R-1234yf in the engine compartment during a frontal collision. This paper will discuss the process followed in the methodology, the technical rationale for this process, and the results of the analysis. The specific types of analysis included in the methodology are: exhaust-system thermal characterization, computer simulated crash tests, actual crash tests, teardown and examination of crashed parts, and releases of refrigerant onto hot exhaust manifolds. Each type of analysis was logically ordered and combined to produce a comprehensive evaluation methodology. This methodology has been applied and demonstrates that R-1234yf is difficult to ignite when factors that occur in frontal crashes are simultaneously considered.

Compressed natural gas (CNG) currently is used as an alternative fuel for internal combustion engines in motor vehicles. This paper presents results of an analysis of leaks from a model isolated section of CNG fuel system. Discharge of CNG was modeled as vent flow of a real gas hydrocarbon mixture through an orifice from a reservoir with finite volume. Pressures typically used in CNG fuel systems result in choked flow for gas venting directly to atmosphere, producing an under-expanded, momentum-dominated, turbulent free jet with well defined velocity and concentration fields. This paper presents results of analyses of reservoir pressure decay, and vent flow and concentrations fields for CNG venting from a pressurized reservoir into the atmosphere. A combination of empirically-derived analytical relationships and detailed two-dimensional high resolution computational fluid dynamic modeling was used to determine the velocity and concentrations fields of the resulting CNG jet.

A prototype fire suppression system was tested in one full-scale vehicle crash tests and three static vehicle fire tests. The prototype fire suppression system consisted of 2 Solid Propellant Gas Generators and two optical detectors. These components were installed on the hood of the test vehicle. A vehicle crash test and a series of static vehicle fire tests were performed to determine the effectiveness of this prototype fire suppression systems in extinguishing fires in the engine compartment of a crashed vehicle

Flammability tests were conducted on one control HVAC module and two experimental automotive HVAC modules containing flame retardant chemicals. The HVAC modules were exposed to a heptane pool fire. All three HVAC modules burned under these conditions. The mass loss rates of the control and experimental HVAC modules were similar. The flame retardant chemicals caused a 50% reduction in the heat produced, a 751 - 897% increase in the carbon monoxide produced, a 4,867 - 5,567% increase in the gaseous hydrocarbon produced, and a 3,875 - 4,725% increase in the smoke produced when the HVAC modules burned under these conditions. These quantitative results are consistent with visual observations made during these tests that the experimental HVAC modules produced substantially more smoke than the control HVAC module.