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Ion sensors have been shown to be a low-cost and robust method of measuring start of combustion (SOC) in Homogeneous Charge Compression Ignition (HCCI) engines. The combustion event in an HCCI engine is governed by temperature sensitive chemical-kinetics and is highly fuel dependent. Autoignition variability between various fuels can also affect emissions, efficiency, and overall operating range of the HCCI engine. Ion sensors (i.e. modified spark-plugs) can be used pragmatically to detect the combustion event for various fuels in HCCI engines over a wide range of operating conditions. An investigation of the ion currents produced from the combustion of gasoline, ethanol, and n-heptane in a 1.9L 4-cylinder VW TDI diesel engine (converted to run in HCCI mode) is conducted over a range of equivalence ratios, intake temperatures, and intake pressures. Gasoline, ethanol and n-heptane have diverse autoignition characteristics which affect the overall operation of the HCCI engine.

The improvement of the indicated thermal efficiency of an argon power cycle (replacing nitrogen with argon in the combustion reaction) is investigated in a CFR engine at high compression ratios in homogeneous charge compression ignition (HCCI) mode. The study combines the two effects that can increase the thermodynamic efficiency as predicted by the ideal Otto cycle: high specific heat ratio (provided by argon), and high compression ratios. However, since argon has relatively low heat capacity (at constant volume), it results in high in-cylinder temperatures, which in turn, leads to the occurrence of knock. Knock limits the feasible range of compression ratios and further increasing the compression ratio can cause serious damage to the engine due to the high pressure rise rate caused by advancing the combustion phasing.

The downsizing of internal combustion engines to increase fuel economy leads to challenges in both obtaining ignition and stabilizing combustion at boosted intake pressures and high exhaust gas recirculation dilution conditions. The use of non-thermal plasma ignition technologies has shown promise as a means to more reliably ignite dilute charge mixtures at high pressures. Despite progress in fundamental research on this topic, both the capabilities and operation implications of emerging non-thermal plasma ignition technologies in internal combustion engine applications are not yet fully explored. In this work, we document the effects of using a corona discharge ignition system in a single cylinder gasoline direct injection research engine relative to using a traditional inductive spark ignition system under conditions associated with both naturally aspirated (8 bar BMEP) and boosted (20 bar BMEP) loads at moderate (2000 rpm) and high (4000 rpm) engine speeds.

Researchers have known about a higher pre-ignition frequency of alcohol fuels for several decades now. Several studies, assessing the effect of ethanol addition on stochastic pre-ignition, have shown contradicting observations. Researchers at FEV observed an increase in pre-ignition frequency with an increase in ethanol concentration, however the pre-ignition events at high ethanol content did not lead to super-knock. Most of the studies have used varying ethanol fraction in a common base-fuel, thereby varying the auto-ignition tendency of the blend. In the current study, the effect of ethanol addition on FACE (Fuels for Advanced Combustion Engines) gasolines is assessed. Five different FACE gasolines (FACE A, C, I, J and G) were used for the study. Ignition delay time of varying ethanol fractions in FACE gasolines was measured in an Ignition Quality Tester (IQT), following ASTM 6890.

Textbook engine thermodynamics predicts that SI (Spark Ignition) engine efficiency η is a function of both the compression ratio CR of the engine and the specific heat ratio γ of the working fluid. In practice the compression ratio of the SI engine is often limited due to “knock”. Knock is in large part the effect of end gases becoming too hot and auto-igniting. Knock results in increase in heat transfer to the walls which negatively affects efficiency. Not to mention damages to the piston. One way to lower the end-gas temperature is to cool the intake gas before inducting it into the combustion chamber. With colder intake gases, higher CR can be deployed, resulting in higher efficiencies. In this regard, we investigated the efficiency of a standard Waukesha CFR engine. The engine is operated in the SI engine mode, and was operated with two differing mixtures at different temperatures.

Development of SI engines to further increase engine efficiency is strongly affected by the occurrence of engine knock. Engine knock has been widely investigated over the years and the main promoting parameters have been identified as load (temperature and pressure), mixture composition, engine speed, characteristic of the fuel, combustion chamber design, and etc. In this paper a new model for predicting engine knock in 0-D environment is presented. The model is based on the well-known approach of using a Livengood and Wu knock integral. Ignition delay data that are supplied to the knock integral are for specific fuel calculated by detail chemical kinetics and are comprised of low temperature heat release ignition delay and high temperature heat release ignition delay. Next, the cycle to cycle variations of engine and temperature stratification of the end gas have to be taken into account.

We have converted a Caterpillar 3406 natural gas spark ignited engine to HCCI mode and used it as a test bed for demonstrating advanced control methodologies. Converting the engine required modification of most engine systems: piston geometry, starting, fueling, boosting, and (most importantly) controls. We implemented a thermal management system consisting of a recuperator that transfers heat from exhaust to intake gases and a dual intake manifold that permits precise cylinder-by-cylinder ignition control. Advanced control methodologies are used for (1) minimizing cylinder-to-cylinder combustion timing differences caused by small variations in temperature or compression ratio; (2) finding the combustion timing that minimizes fuel consumption; and (3) tuning the controller parameters to improve transient response.

Experimental tests were conducted on a Cummins B5.9 direct-injected diesel engine fueled with biodiesel blends. 20% and 50% blend levels were tested, as was 100% (neat) biodiesel. Emissions of particulate matter (PM), nitrogen oxides (NOx), hydrocarbons (HC) and CO were measured under steady-state operating conditions. The effect of biodiesel on total PM emissions was mixed; however, the contribution of the volatile organic fraction to total PM was greater for higher biodiesel blend levels. When only non-volatile PM mass was considered, reductions were observed for the biodiesel blends as well as for neat biodiesel. The biodiesel test fuels increased NOx, while HC and CO emissions were reduced. PM collected on quartz filters during the experimental runs were analyzed for carbon-14 content using accelerator mass spectrometry (AMS).

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers.

We present the effect of EGR, at a set fuel flow rate and intake temperature, on the operating parameters of timing of combustion, duration of combustion, power output, thermal efficiency, and NOx emission; which is remarkably low. We find that addition of EGR at constant inlet temperature and constant fuel flow rate has little effect on HCCI parameter of start of combustion (SOC). However, burn duration is highly dependent on the amount of EGR inducted. The experimental setup at UC Berkeley uses a 1.9-liter 4-cylinder diesel engine with a compression ratio of 18.8:1 (offered on a 1995 VW Passat TDI). The engine was converted to run in HCCI mode by addition of an 18kW air pre-heater installed in the intake system. Pressure traces were obtained using four water-cooled quartz pressure transducers, which replaced the Diesel fuel injectors. Gaseous fuel (propane or butane) flowed steadily into the intake manifold.

A four-cylinder 1.9 Volkswagen TDI Engine has been converted to run in Homogeneous Charge Compression Ignition (HCCI) mode. The stock configuration is a turbo-charged direct injection Diesel engine. The combustion chamber has been modified by discarding the in-cylinder Diesel fuel injectors and replacing them with blank inserts (which contain pressure transducers). The stock pistons contain a reentrant bowl and have been retained for the tests reported here. The intake and exhaust manifolds have also been retained, but the turbocharger has been removed. A heater has been installed upstream of the intake manifold and fuel is added just downstream of this heater. The performance of this engine in naturally aspirated HCCI operation, subject to variable intake temperature and fuel flow rate, has been studied. The engine has been run with propane fuel at a constant speed of 1800 rpm.

This research investigates a control system for HCCI engines, where equivalence ratio, fraction of EGR and intake pressure are adjusted as needed to obtain satisfactory combustion. HCCI engine operation is analyzed with a detailed chemical kinetics code, HCT (Hydrodynamics, Chemistry and Transport), that has been extensively modified for application to engines. HCT is linked to an optimizer that determines the operating conditions that result in maximum brake thermal efficiency, while meeting the peak cylinder pressure restriction. The results show the values of the operating conditions that yield optimum efficiency as a function of torque and rpm. The engine has high NOx emissions for high power operation, so the possibility of switching to stoichiometric operation for high torque conditions is considered. Stoichiometric operation would allow the use of a three-way catalyst to reduce NOx emissions to acceptable levels.

This paper describes the Homogeneous charge compression ignition (HCCI) research activities being currently pursued at Lawrence Livermore National Laboratory and at the University of California Berkeley. Current activities include analysis as well as experimental work. HCCI is an old combustion technology that may now be developed with expectations of high efficiency, low NOx, and low particulate matter emissions; in short, an alternative to diesel engines. On analysis, we have developed two powerful tools: a single zone model and a multi-zone model. The single zone model has proven very successful in predicting start of combustion and providing reasonable estimates for peak cylinder pressure, indicated efficiency and NOX emissions. This model is being applied to develop detailed engine performance maps and control strategies, and to analyze the problem of engine startability.

Engine fuel tests were conducted with an oxygenated fuel called Cetaner blended with conventional diesel fuel to determine its emissions reduction potential. Blends of 10, 20, 30 and 40% by volume were investigated. The test engine was a 1993 Cummins B5.9 diesel rated at 175 hp. Emissions of particulate matter (PM), oxides of nitrogen (NOx), hydrocarbons (HC) and carbon monoxide (CO), along with brake specific fuel consumption (bsfc) were measured during steady state operation at eight engine speed-load conditions. Soluble organic fraction (SOF) analysis was also carried out on the collected PM filter samples. The experimental results showed that the Cetaner blends can substantially reduce PM emissions. Reductions were observed in both the organic and inorganic fractions of the collected PM. On a modal-averaged basis, increasing Cetaner blend levels yielded greater PM reductions, with reductions of about 3-4% observed for each 1% of oxygen blended to the fuel by mass.

This research work has focused on measuring the effect of fuel/air mixing on performance and emissions for a homogeneous charge compression ignition engine running on propane. A laser instrument with a high-velocity extractive probe was used to obtain time-resolved measurements of the fuel concentration both at the intake manifold and from the cylinder for different levels of fuel-air mixing. Cylinder pressure and emissions measurements have been performed at these mixing levels. From the cylinder pressure measurements, the IMEP and peak cylinder pressure were found. The fuel-air mixing level was changed by adding the fuel into the intake system at different distances from the intake valve (40 cm and 120 cm away). It was found that at the intake manifold, the fuel and air were better mixed for the 120 cm fuel addition location than for the 40 cm location.

The addition of oxygenates to diesel fuel reduces particulate emissions, but the mechanisms responsible for the reductions are not well understood. Measurement of particulate matter (PM), unburned hydrocarbons (HC), and carbon monoxide (CO) are routine, but determining the origin of the carbon atoms that make up these undesired emissions is difficult. The sub-attomole (<6×105 atoms) sensitivity of accelerator mass spectrometry (AMS) for measuring carbon-14 (14C) allows tracing the carbon atoms from specific fuel components to soot or gaseous emissions. Radioactive materials are not required because contemporary carbon (e.g., ethanol from grain) has 1000 times more 14C than petroleum-derived fuels. The specificity of the 14C tracer and the sensitivity of AMS were exploited to investigate the relative contribution to diesel engine PM, CO, and CO2 from ethanol and diesel fractions of blended fuels.

A summary is presented of experimental results obtained from a Cummins B5.9 175 hp, direct-injected diesel engine fueled with oxygenated diesel blends. The oxygenates tested were dimethoxy methane (DMM), diethyl ether, a blend of monoglyme and diglyme, and ethanol. The experimental results show that particulate matter (PM) reduction is controlled largely by the oxygen content of the blend fuel. For the fuels tested, the effect of chemical structure was observed to be small. Isotopic tracer tests with ethanol blends reveal that carbon from ethanol does contribute to soot formation, but is about 50% less likely to form soot when compared to carbon from the diesel portion of the fuel. Numerical modeling was carried out to investigate the effect of oxygenate addition on soot formation. This effort was conducted using a chemical kinetic mechanism incorporating n-heptane, DMM and ethanol chemistry, along with reactions describing soot formation.

The addition of oxygenates to diesel fuel can reduce particulate emissions, but the underlying chemical pathways for the reductions are not understood. While measurements of particulate matter (PM), unburned hydrocarbons (HC), and carbon monoxide (CO) are routine, determining the contribution of carbon atoms in the original fuel molecules to the formation of these undesired exhaust emissions has proven difficult. Using accelerator mass spectrometry (AMS) diagnostics, carbon atoms in a specific bond position in a specific fuel molecule can be labeled with carbon-14 (14C) and traced through the combustion event to determine whether they reside in PM, HC, CO, CO2, or other emission products. This knowledge of how specific molecular structures produce certain emissions can be used to refine chemical-kinetic combustion models and to optimize fuel composition to reduce undesired emissions.

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. The methodology judiciously uses a fluid mechanics code followed by a chemical kinetics code to achieve great reduction in the computational requirements; to a level that can be handled with current computers. In previous papers, our sequential, multi-zone methodology has been applied to HCCI combustion of short-chain hydrocarbons (natural gas and propane). Applying the same procedure to long-chain hydrocarbons (iso-octane) results in unacceptably long computational time. In this paper, we show how the computational time can be made acceptable by developing a segregated solver. This reduces the run time of a ten-zone problem by an order of magnitude and thus makes it much more practical to make combustion studies of long-chain hydrocarbons.

This paper shows how a computer can systematically remove non-essential chemical reactions from a large chemical kinetic mechanism. The computer removes the reactions based upon a single solution using a detailed mechanism. The resulting reduced chemical mechanism produces similar numerical predictions significantly faster than predictions that use the detailed mechanism. Specifically, a reduced chemical kinetics mechanism for iso-octane has been derived from a detailed mechanism by eliminating unimportant reaction steps and species. The reduced mechanism has been developed for the specific purpose of fast and accurate prediction of ignition timing in an HCCI engine. The reduced mechanism contains 199 species and 383 reactions, while the detailed mechanism contains 859 species and 3606 reactions. Both mechanisms have been used in numerical simulation of HCCI combustion.