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Stoichiometric natural gas engines with three-way catalysts emit less NOx and CH4 due to their higher efficiency compared to lean-burn natural gas engines. Although hydrothermal aging of three-way catalysts has been extensively studied, a deeper understanding beyond hydrothermal aging is needed to explain real-world performance, especially for natural gas engines with near-zero NOx emissions. In this investigation, field-aged three-way catalysts were characterized to identify the contribution of chemical aging to their overall performance. It was found that the sulfur species on the field-aged TWCs were entirely distributed along the catalyst length, showing a decreasing trend, whereas phosphorous contamination was mainly observed at the inlet section of the three-way catalysts, and the phosphorous concentration declined sharply along the axial length.

Future light duty vehicles in the United States are required to be certified on the FTP-75 cycle to meet Tier 3 or LEV III emission standards [1, 2]. The cold phase of this cycle is heavily weighted and mitigation of emissions during this phase is crucial to meet the low tail pipe emission targets [3, 4]. In this work, a novel aftertreatment architecture and controls to improve Nitrogen Oxides (NOx) and Hydrocarbon (HC) or Non Methane Organic gases (NMOG) conversion efficiencies at low temperatures is proposed. This includes a passive NOx & HC adsorber, termed the diesel Cold Start Concept (dCSC™) catalyst, followed by a Selective Catalytic Reduction catalyst on Filter (SCRF®) and an under-floor Selective Catalytic Reduction catalyst (SCR). The system utilizes a gaseous ammonia delivery system capable of dosing at two locations to maximize NOx conversion and minimize parasitic ammonia oxidation and ammonia slip.

Measuring axial exhaust species concentration distributions within a wall-flow aftertreatment device provides unique and significant insights regarding the performance of complex devices like the SCR-on-filter. In this particular study, a less complex aftertreatment configuration which includes a DOC followed by two uncoated partial flow filters (PFF) was used to demonstrate the potential and challenges. The PFF design in this study was a particulate filter with alternating open and plugged channels. A SpaciMS [1] instrument was used to measure the axial NO2 profiles within adjacent open and plugged channels of each filter element during an extended passive regeneration event using a full-scale engine and catalyst system. By estimating the mass flow through the open and plugged channels, the axial soot load profile history could be assessed.

In this paper we consider the issues facing the design of a practical multivariable controller for a diesel engine with dual exhaust gas recirculation (EGR) loops. This engine architecture requires the control of two EGR valves (high pressure and low pressure), an exhaust throttle (ET) and a variable geometry turbocharger (VGT). A systematic approach suitable for production-intent air handling control using Model Predictive Control (MPC) for diesel engines is proposed. Furthermore, the tuning process of the proposed design is outlined. Experimental results for the performance of the proposed design are implemented on a 2.8L light duty diesel engine. Transient data over an LA-4 cycle for the closed loop performance of the controller are included to prove the effectiveness of the proposed design process.

NOx sorbate, or “trap”, catalysts have achieved >90% reduction of NOx from lean exhaust streams over a broad range of temperatures. Since diesel can be used as the reductant for NOx sorbate catalysts, the sorbate catalyst technology offers great potential for NOx control in a broad range of mobile diesel applications. Traditionally, the longevity of NOx sorbate catalysts in diesel exhaust applications has been limited by sulfur masking of NOx sorption sites. Two methods to control sulfur compounds and their associated effects will be presented here. Upstream sulfur sorbate, or “trap”, catalysts are used to control the rate of sulfur masking by diverting sulfur away from the NOx sorbate catalyst. Desulfation of NOx sorbate catalysts can lead to the removal of sulfur compounds from the catalyst and reactivation of NOx sorption sites. Data demonstrating sulfur control with both of these methods will be presented here.

High-speed diagnostics capable of accurately resolving emission transients are required to provide the most detailed understanding and optimization of active exhaust-emissions-treatment processes, such as NOX adsorbers. A portable, mass-spectrometry-based instrument with high temporal resolution, linear response and broad dynamic range is described. This instrument provides transient-concentration measurement capability for many relevant exhaust species including total NOX. In applications for evaluation of NOX-adsorber systems using heavy-duty diesel engines, the instrument revealed relevant emission transients not previously resolved with conventional analyzers. Specifically, the instrument resolved transient emissions associated with the competition between desorption and reduction rates. The temporal resolution of the instruments is sufficient to resolve kinetic rates of the NOX-adsorber system.