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A gasoline’s distillation profile is directly related to its hydrocarbon composition and the volatility (boiling points) of those hydrocarbons. Generally, the volatility profiles of U.S. market fuels are characterized using a very simple, low theoretical plate distillation separation, detailed in the ASTM D86 test method. Because of the physical chemistry properties of some compounds in gasoline, this simple still or retort distillation has some limitations: separating azeotropes, isomers, and heavier hydrocarbons. Chemists generally rely on chromatographic separations when more detailed and precise results are needed. High-boiling aromatic compounds are the primary source of particulate emissions from spark ignited (SI), internal combustion engines (ICE), hence a detailed understanding and high-resolution separation of these heavy compounds is needed.

Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.

Automakers are designing smaller displacement engines with higher power densities to improve vehicle fuel economy, while continuing to meet customer expectations for power and drivability. The specific power produced by the spark-ignited engine is constrained by knock and fuel octane. Whereas the lowest octane rating is 87 AKI (antiknock index) for regular gasoline at most service stations throughout the U.S., 85 AKI fuel is widely available at higher altitudes especially in the mountain west states. The objective of this study was to explore the effect of gasoline octane rating on the net power produced by modern light duty vehicles at high altitude (1660 m elevation). A chassis dynamometer test procedure was developed to measure absorbed wheel power at transient and stabilized full power operation. Five vehicles were tested using 85 and 87 AKI fuels.

Modification of gasoline blendstock composition in preparing ethanol-gasoline blends has a significant impact on vehicle exhaust emissions. In “splash” blending the blendstock is fixed, ethanol-gasoline blend compositions are clearly defined, and effects on emissions are relatively straightforward to interpret. In “match” blending the blendstock composition is modified for each ethanol-gasoline blend to match one or more fuel properties. The effects on emissions depend on which fuel properties are matched and what modifications are made, making trends difficult to interpret. The purpose of this paper is to illustrate that exclusive use of a match blending approach has fundamental flaws. For typical gasolines without ethanol, the distillation profile is a smooth, roughly linear relationship of temperature vs. percent fuel distilled.

This study investigates the effects of octane quality on the performance, i.e., acceleration and power, and fuel economy (FE) of one late model US vehicle, which is powered by a small displacement, turbocharged, gasoline direct injection (GDI) engine. The relative importance of the gasoline parameters Research and Motor Octane Number (RON and MON) in meeting the octane requirement of this engine to run at an optimum spark timing for the given demand was considered by evaluating the octane index (OI), where OI = (1-K) RON + K MON and K is a constant depending on engine design and operating conditions. Over wide open throttle (WOT) accelerations, the average K of this Pontiac Solstice was determined as −0.75, whereby a lower MON would give a higher OI, a higher knock resistance and better performance.

Classic, hot-spot induced pre-ignition is a phenomenon that has been observed in gasoline spark ignited engines over the past 60-70 years. With the development of turbocharged, direct-injected (DI) gasoline engines, a new pre-ignition phenomenon occurring at low engine speeds and high loads has been encountered. Termed Stochastic Pre-ignition (SPI), it has become a significant issue to address in allowing for the full potential of gasoline turbo DI technology to improve powertrain efficiency. Many researchers are studying all aspects of the causes of Stochastic Pre-ignition, including causes by oil, fuel and engine hardware systems. The focus of this specific research was to study the relationship of fuel octane and volatility to Stochastic Pre-ignition behavior utilizing a GM 2.0L Gasoline Turbocharged DI engine (LHU).

The U.S. Renewable Fuel Standard 2 (RFS2) mandates the use of advanced renewable fuels such as cellulosic ethanol to be blended into gasoline in the near future. As such, determining the impact of these new fuel blends on vehicle performance is important. Therefore, General Motors conducted engine dynamometer evaluations on the impact of cellulosic ethanol blends on port fuel injected (PFI) intake valve deposits and gasoline direct injected (GDI) fuel injector plugging. Chemical analysis of the test fuels was also conducted and presented to support the interpretation of the engine results. The chemical analyses included an evaluation of the specified fuel parameters listed in ASTM International's D4806 denatured fuel ethanol specification as well as GC/MS hydrocarbon speciations to help identify any trace level contaminant species from the new ethanol production processes.

With the increasing use of ethanol blended motor fuels around the world, vehicle manufacturers as well as ethanol producers and distributors are interested in understanding ethanol's effects on materials corrosion. More specifically, General Motors continually evaluates fuel effects on fuel system materials and overall engine performance, and is studying the corrosive effects of chloride ions present in ethanol blended fuels, even at low part per million (ppm) levels. Chloride ions present in chemically polar motor fuels such as E85 are known to be one of the primary species involved in general pitting corrosion, galvanic corrosion, and stress corrosion cracking of automotive components. The authors conducted a 50K mile vehicle test program studying the performance and durability of two E85 Flex Fuel Vehicles (FFV) operating on E85, with specified ppm levels of chlorides.

With the wider use of Direct Injection Spark Ignition (DISI) vehicles in the marketplace, a program was conducted to develop a short-duration fuel injector fouling test. Once a specific driving cycle and base fuel combination was found to produce a significant increase in Long Term Fuel Trim (LTFT), several Deposit Control Additive (DCA) technologies were evaluated for their ability to keep the direct gasoline injectors clean. The increase in LTFT is indicative of fuel injector fouling and a corresponding decrease in flow through them. The test vehicles for this program were a 2008 General Motors Pontiac Solstice GXP equipped with a DISI 2.0 liter turbocharged I-4 and a 2008 Audi A4 equipped with a DISI 3.2 liter V-6 engine. A proprietary base fuel formulated to mimic a U.S. EPA 65th percentile fuel was tested to assess its deposit forming tendencies.

Cold start vehicle driveability performance depends on many parameters, one of which is the distillation character of the fuel. In the late 90's, a gasoline driveability index (DI) was developed for spark ignited combustion vehicles by a consortium of automotive and petroleum industry scientists based on correlation studies between controlled fuel quality matrices and vehicle performance under specific ambient conditions. The DI equation uses a weighted sum of gasoline distillation temperatures at the 10, 50 and 90 percent evaporation volumes, commonly called T10, T50 and T90. These three distillation volatility points are specified by the ASTM International D 4814 fuel specification and are seasonally adjusted. This paper studies the cold start driveability performance of Federal EPA Bin 5 and Bin 8 vehicles with respect to fuel distillation characteristics at temperatures other than T10, T50 and T90.