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Catalyzed gasoline particulate filters (cGPF) are one of the most effective emission control technologies for reducing gaseous and particulate emissions simultaneously. Successful adoption of this advanced technology relies on several important performance properties including low back pressure, high filtration efficiency and specially durability compliance. In this work using an underfloor cGPF, the backpressure control was achieved through optimizing catalyst coating technology and modifying the deposition profile of catalyst coating along GPF channels. Durability performance was demonstrated by using an accelerated engine aging method with selective blending of lubricating oils in fuel, which incorporates the aging mechanisms of thermal aging, ash loading, and soot accumulation/regeneration. The target durability demonstration represents 200,000 km real world operation.

Catalyzed gasoline particulate filter (cGPF) is the prime technology to meet future stringent regulations for particulates from gasoline direct injection (GDI) engines. One of the technical concerns is the ultimate durability of cGPF in regards to engine lubricant formulations. This study investigated two tailored lubricant formulations on catalyzed GPFs which were aged on engine followed by emission testing on vehicle. An engine accelerated aging protocol was developed for cGPFs to simulate thermal aging, ash and soot loading that is at least equivalent to 200,000 km durability requirement. Evaluations include tailpipe emission levels, backpressure, catalytic performance, and post-mortem analysis. Both formulations have demonstrated a high level of cGPF performance retention; performance being assessed in terms of emission level at the end of durability demonstration testing. These formulations provide flexibility in selecting robust lubricant to meet various system requirements.

Because of the increased use of gasoline direct engine (GDI) in the automobile industry, there is a significant need to control particulates from GDI engines based on emission regulations. One potential technical approach is the utilization of a gasoline particulate filter (GPF). The successful adoption of this emission control technology needs to take many aspects into consideration and requires a system approach for optimization. This study conducted research to investigate the impact of vehicle driving cycles, fuel properties and catalyst coating on the performance of GPF. It was found that driving cycle has significant impact on particulate emission. Fuel quality still plays a role in particulate emissions, and can affect the GPF performance. Catalyzed GPF is preferred for soot regeneration, especially for the case that the vehicle operation is dominated by congested city driving condition, i.e. low operating temperatures. The details of the study are presented in the paper.

Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.

Mobile source emissions standards are becoming more stringent and particulate emissions from gasoline direct injection (GDI) engines represent a particular challenge. Gasoline particulate filter (GPF) is deemed as one possible technical solution for particulate emissions reduction. In this work, a study was conducted on eight formulations of lubricants to determine their effect on GDI engine particulate emissions and GPF performance. Accelerated ash loading tests were conducted on a 2.4L GDI engine with engine oil injection in gasoline fuel by 2%. The matrix of eight formulations was designed with changing levels of sulfated ash (SASH) level, Zinc dialkyldithiophosphates (ZDDP) level and detergent type. Comprehensive evaluations of particulates included mass, number, size distribution, composition, morphology and soot oxidation properties. GPF performance was assessed through filtration efficiency, back pressure and morphology.

A conceptual approach to help understand and simulate droplet induced pre-ignition is presented. The complex phenomenon of oil-fuel droplet induced pre-ignition has been decomposed to its elementary processes. This approach helps identify the key fluid properties and engine parameters that affect the pre-ignition phenomenon, and could be used to control LSPI. Based on the conceptual model, a 3D CFD engine simulation has been developed which is able to realistically model all of the elementary processes involved in droplet induced pre-ignition. The simulation was successfully able to predict droplet induced pre-ignition at conditions where the phenomenon has been experimentally observed. The simulation has been able to help explain the observation of pre-ignition advancement relative to injection timing as experimentally observed in a previous study [6].

The rapid advancement of diesel engine technology as used in European passenger cars brings greater demands for the provision of high-quality diesel fuel and premium performance fuels. Fuel additives play an increasingly important role in enhancing fuel quality and meeting the demands of these new engine technologies. The development of these additives and appropriate fuels relies on engine test procedures that can accurately simulate the performance of the fuel in consumer vehicles. The value of such tests is greatest when the test cycle, operating parameters and test fuel have relevant correlation to those experienced by a vehicle in actual consumer use. This paper considers the DW10 injector fouling test currently under development within the CEC and highlights the methods used to increase the severity. Conventional fuel additives currently used in premium fuels offer superb protection against the deposit formation seen in this test.

Since the introduction of the catalytic converter, some automobile manufacturers have questioned whether the converter is compatible with the use of the gasoline fuel additive MMT®. Concerns have generally revolved around possible interactions between combustion products of MMT® (i.e., manganese containing compounds) and catalytic converters. In particular, concern has been raised over the possibility that MMT® combustion products physically “plug” the catalyst and cause catalyst failure, where plugging refers to blockage of contiguous pores at the catalyst inlet face or within the body of the converter. In modern vehicles this could result in the illumination of the malfunction indicator light (MIL) due to storing of an on-board diagnostic (OBD) failure code pertaining to catalyst operation or failure of a vehicle inspection and maintenance (I/M) test.

This paper presents the results of a three city survey designed to determine the relative frequency of illumination of vehicle on-board diagnostic (OBD) malfunction indicator lights (MIL) on 2001 and later model year vehicles. The survey was conducted in a Canadian market, Regina, and two U.S. markets, Minneapolis and Denver, to assess claims that the presence of methycyclopentadienyl manganese tricarbonyl (MMT®) in gasoline causes the failure of technology necessary to meet stringent Tier 2 emission standards applicable in North America. The results of the survey do not support the claim that MMT® is incompatible with the effective functioning of the advanced vehicle emission technology necessary to meet Tier 2 emission standards. The results substantiate that the performance of the most advanced vehicles operating on gasoline containing MMT® is not materially different from the performance of comparable vehicles operating on gasoline that does not contain MMT®.

This report describes the results of a fleet test conducted with vehicles certified to Euro IV standards and equipped with high cell density close coupled manifold mounted catalysts. The purpose of the test was to determine the effect of MMT® on vehicle emission system durability under severe in-service operating conditions and to address vehicle manufacturers concerns about the effects of MMT® in advanced technology vehicles. The results clearly show that performance and durability of the vehicles are not affected even under severe operating conditions when MMT® is used in the gasoline. Two pairs each of Volkswagen Passats and Opel Corsas (eight vehicles total) were operated on a base fuel and a base fuel splash blended with MMT® at a concentration of 18 milligrams manganese per liter (“mg Mn/l”). The vehicles accumulated mileage on a driving regime representative of severe service.

In July 2002, the Alliance of Automobile Manufacturers, the Association of International Automobile Manufacturers and the Canadian Vehicle Manufacturers Association released the results of a 6-year, two-part vehicle fleet test program to determine the effects of methyl-cyclopentadienyl manganese tricarbonyl (MMT®*) on vehicles equipped with state of the art emission control systems. Analysis of the data reports from this study shows that all of the vehicles met applicable emission standards, even though the fleet accumulated mileage under very severe conditions that accelerate degradation of vehicle emission control systems in excess of that expected from actual vehicle mileage. The study also demonstrated that gasoline-containing MMT had no adverse impact on vehicular emission control equipment.

Control and elimination of mobil-source particulate matter (PM) emissions is of increasing interest to engineers and scientists as regulators in industrialized countries promulgate lower emission levels in diesel engines. Relative to their gasoline engine counterparts, today's diesel engines, in general, still emit a higher mass of PM. While strictly speaking, this PM is an agglomeration of organic and inorganic particles, the predominant component is carbon and is commonly referred to as “soot”. For mobil-source PM control, one of the current preferred technologies is the ceramic closed-cell monolith Diesel Particulate Filter (DPF). Ideally, DPFs accumulate and store PM during low speed/temperature engine operation and burn the accumulated PM during high speed/temperature operation.

Throughout the world, governments are promulgating regulations that are intended to improve air quality. Some of these regulations affect the physical and chemical properties of gasoline. Consequently, refiners are under increasing pressure to reformulate their gasoline to be lower emitting when handled and combusted. These regulatory actions have also greatly reduced flexibility in the fuel formulation process. In many cases, refiners are attempting to reduce gasoline vapor pressure, sulfur, aromatic, and olefin content while simultaneously tightening distillation characteristics by removing butane and reducing the use of heavy reformate and FCC fractions. Because butane, aromatics and olefins can contribute substantially to pool octane levels, blending clean-burning gasoline with the required octane rating for acceptable vehicle performance can be difficult.

SAE Paper 2002-01-2894 entitled, “The Impact of MMT Gasoline Additive on Exhaust Emissions and Fuel Economy of Low Emission Vehicles (LEV)” presents discussion and conclusions concerning the emissions from vehicles that accumulated mileage on gasoline with and without the fuel additive, methylcyclopentadienyl manganese tricarbonyl (or MMT®). Although the authors of the paper express concern about use of MMT®, the data on which the authors rely are consistent with the results and conclusions from prior evaluations of MMT® which have found that MMT® is compatible with effective emission control system operation (1,2,3). All vehicles tested in the study met the emission standards for all pollutants that apply to the test vehicles in-use and analysis of the data show MMT® had no effect on fuel economy.

The long-term durability of a vehicle's exhaust catalyst is essential for emission control. Catalyst durability can be affected by a variety of factors including engine oil consumption. During normal engine operation, some of the lubricating oil is combusted. The deposition of combustion products from phosphorus containing lubricant additives on the catalyst can adversely affect catalyst durability. In an attempt to minimize the impact of oil consumption on additive performance, engines have been designed to reduce oil consumption and oils are being formulated with lower concentrations of phosphorus compounds. However, these phosphorus compounds protect the engine from excessive wear and cannot be easily removed from lubricant oil due to concerns over engine durability. The use of a phosphorus scavenger is an approach that works together with engine design to minimize catalyst deterioration.

Greenhouse gas emissions (GHG) from light-duty vehicles have received attention recently because of increased focus on global warming and climate change. Relative to emissions of regulated pollutants like hydrocarbons and nitrogen oxides, nitrous oxide (N2O) emissions from all vehicles are generally very low. However, N2O is a powerful greenhouse gas, and small emissions of N2O can contribute substantially to total GHG inventories. Two fleets of different vehicle models, both meeting the current US Tier 1 emission standard, were evaluated in an effort to develop a better understanding of N2O emissions from modern three-way catalyst-equipped vehicles. Nine 1997 Ford Crown Victoria vehicles operating on clean-burning US Federal Phase 2 Reformulated Gasolines were assessed over 60,000 miles. For additional comparison, testing was also conducted with catalysts from six 1994 Toyota Camry vehicles, which had previously undergone 110,000 miles of controlled mileage accumulation.