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One of the most critical aspects in the development of a kinetic model for automotive applications is the method used to control the switch between limiting factors over the period of the chemical reaction, namely mass transfer and reaction kinetics. This balance becomes increasingly more critical with the automotive application with the gas composition and gas flow varying throughout the automotive cycles resulting in a large number of competing reactions, with a constantly changing space velocity. A methodology is presented that successfully switches the limitation between mass transfer and reaction kinetics. This method originally developed for the global kinetics model using the Langmuir Hinshelwood approach for kinetics is presented. The methodology presented is further expanded to the much more complex micro-kinetics approach taking into account various kinetic steps such as adsorption/desorption and surface reactions.

The results of this paper will show the reader how to quantify a minimum light-off temperature to meet the required emissions standards with the use of a 3-way catalytic converter. The method can be applied to both motorcycle and larger automotive catalysts to help meet their respective emissions standards (Euro 5/Euro 7). The ability to predict a light-off temperature for any catalyst at the beginning of the project saves both time and resource. With an emphasis on how the shape of the light-off curve affects the cumulative tailpipe emissions and how shape of the light-off curves change with the ageing process. Changes in the light-off curves will be reviewed to understand how the chemical reactions and pore diffusion mechanisms within the catalyst deplete to negatively affect performance over its life time.

This study describes an innovative monolith structure designed for applications in automotive catalysis using an advanced manufacturing approach developed at Imperial College London. The production process combines extrusion with phase inversion of a ceramic-polymer-solvent mixture in order to design highly ordered substrate micro-structures that offer improvements in performance, including reduced PGM loading, reduced catalyst ageing and reduced backpressure. This study compares the performance of the novel substrate for CO oxidation against commercially available 400 cpsi and 900 cpsi catalysts using gas concentrations and a flow rate equivalent to those experienced by a full catalyst brick when attached to a vehicle. Due to the novel micro-structure, no washcoat was required for the initial testing and 13 g/ft3 of Pd was deposited directly throughout the substrate structure in the absence of a washcoat.

The bus sector is currently lagging behind when it comes to implementing autonomous systems for improved vehicle safety. However, in cities such as London, public transport strategies are changing, with requirements being made for advanced driver-assistance systems (ADAS) on buses. This study discusses the adoption of ADAS systems within the bus sector. A review of the on-road ADAS bus trials shows that passive forward collision warning (FCW) and intelligent speed assistance (ISA) systems have been successful in reducing the number of imminent pedestrian/vehicle collision events and improving speed limit compliance, respectively. Bus accident statistics for Great Britain have shown that pedestrians account for 82% of all fatalities, with three quarters occurring with frontal bus impacts.

This paper describes an experimental investigation into the effect of bore/stroke ratio on a simple two-stroke engine. This was achieved with a special purpose engine of modular design. The engine allowed four combinations of bore and stroke to be contrived to yield a common swept volume of 400 cm3 with bore/stroke ratios of: 0.8, 1.0, 1.2 and 1.4. Other factors that might affect engine performance were standardised: the exhaust, intake and ignition systems were common, the combustion chamber designs were similar, scavenge characteristics were similar, port timings and time-areas were kept the same, and cylinder and crankcase compression ratios were also kept the same. The most important conclusions were: Engine power was greatest with the compromise bore/stroke ratio of 1.0 or 1.2. Combustion efficiency tended to decrease with increasing bore/stroke ratio. Mechanical efficiency tended to increase with increasing bore/stroke ratio.

The incorporation of one-dimensional simulation codes within engine modelling applications has proved to be a useful tool in evaluating unsteady gas flow through elements in the exhaust system. This paper reports on an experimental and theoretical investigation into the behaviour of unsteady gas flow through catalyst substrate elements. A one-dimensional (1-D) catalyst model has been incorporated into a 1-D simulation code to predict this behaviour. Experimental data was acquired using a ‘single pulse’ test rig. Substrate samples were tested under ambient conditions in order to investigate a range of regimes experienced by the catalyst during operation. This allowed reflection and transmission characteristics to be quantified in relation to both geometric and physical properties of substrate elements.

Accelerated aging of automotive catalysts has become a routine process for the development of new catalytic formulations and for homologation of vehicle emissions. In the standard approach, catalyst samples are subjected to temperatures in excess of 800°C on a predefined test cycle and aged for precise timescales representative of certain vehicle mileage. The high temperature feed gas is traditionally provided by a large gasoline engine but, increasingly, alternative bench-aging techniques are being applied as these offer more precise control and considerable cost savings, as well as offering more development possibilities. In the past few years, emissions control of light duty vehicles has become increasingly prominent as more stringent emissions legislations require more complex after-treatment systems. Aging of the catalysts are not fully understood as they are subjected to many varying environments, including temperature and gas concentrations.

This paper outlines a novel method employed to accurately age catalysts to the required OBD limit for European motorcycles legalisation Euro 5 using a combination of modelling and testing. The method applies several strategies, including thermal ageing and catalyst poisoning, to reduce catalyst activity in order to mirror real-world catalyst ageing. Predictions were made using a combined global and micro kinetic model to specify catalyst activity to a matching light-off condition. The model simulated a motorcycle operating on a WMTC (World Motorcycle Test Cycle) and adjusted catalyst activity (Precious metal and Oxygen Storage Capacity) until tailpipe emissions matched the limits for Euro 5 OBD II. The same model ran a simulated light-off test to predict the light-off point for the catalyst. The catalyst was then aged to match this light-off performance using a RAT ageing cycle with additional poisoning to reach the target deactivation.

The most common mode of deactivation suffered by catalysts fitted to two-stroke engines has traditionally been thermal degradation, or even meltdown, of the washcoat and substrate. The high temperatures experienced by these catalysts are caused by excessively high concentrations of HC and CO in the exhaust gas which are, in turn, caused by a rich AFR and the loss of neat fuel to the exhaust during the scavenging period. The effects of catalyst poisoning due to additives in the oil is often regarded as a secondary, or even negligible, deactivating mechanism in two-stroke catalysts and has therefore received little attention. However, with the introduction of direct in-cylinder fuel injection to some larger versions of this engine, the quantities of HC escaping to the exhaust can be reduced to levels similar to those found on four-stroke gasoline engines.

Due to stringent emissions legislation, the use of three way catalysts is becoming increasingly prevalent in motorcycles and scooters. This paper describes the development, and subsequent validation, of a detailed mathematical model for the oxygen storage processes in three-way catalysts. The model consists of several interdependent sub-models describing the oxidation and reduction processes and their interaction with a kinetic model of the catalyst. The structure and equations of the model are detailed and their significance discussed. For the validation phase of the work a purpose-built miniature catalyst test rig has been assembled and a series of experiments conducted to assess the oxygen storage processes. Analysis of this data also provided values for the controlling constants associated with the oxidation and reduction reactions. These results are included and compared with other published data.

In this paper a dynamic, modular, 1-D vehicle model architecture is presented which seeks to enhance modelling flexibility and can be rapidly adapted to new vehicle concepts, including hybrid configurations. Interdependencies between model sub-systems are minimized. Each subsystem of the vehicle model follows a standardized signal architecture allowing subsystems to be developed, tested and validated separately from the main model and easily reintegrated. Standard dynamic equations are used to calculate the rotational speed of the desired driveline component within each subsystem i.e. dynamic calculations are carried out with respect to the component of interest. Sample simulations are presented for isolated and integrated components to demonstrate flexibility. Two vehicle test cases are presented.

Vehicle manufacturers face mounting pressure to increase fuel economy and reduce vehicle tailpipe emissions in order to reduce the environmental impact of their vehicles and to meet ever more stringent regulations. Wrightbus have developed first generation single– and double–deck Hybrid Electric Vehicle (HEV) city buses, a number of which are in regular service in London and other cities. These buses utilise a series hybrid powertrain with a turbo-diesel engine, drive motors with total output powers between 120 kW and 170 kW and a DC electrical storage system. Fuel savings up to 30% have been achieved in service. This paper presents a literature review of hybrid vehicle modelling, and covers the work completed by Queen's University to create a software model of the Wrightbus HEV drivetrains in the Mathworks Mat-lab/Simulink environment. The model has been calibrated to several drivetrain configurations, including differing battery technologies, control systems and vehicle hardware.

With a transition towards electric vehicles for the transport sector, there will be greater reliance put upon battery packs; therefore, battery pack modelling becomes crucial during the design of the vehicle. Accurate battery pack modelling allows for: the simulation of the pack and vehicle, more informed decisions made during the design process, reduced testing costs, and implementation of superior control systems. To create the battery cell model using MATLAB/Simulink, an electrical equivalent circuit model was selected due to its balance between accuracy and complexity. The model can predict the state of charge and terminal voltage from a current input. A battery string model was then developed that considered the cell-to-cell variability due to manufacturing defects. Finally, a full battery pack model was created, capable of modelling the different currents that each string experiences due to the varied internal resistance.

With emission legislations becoming ever more stringent there is an increased pressure on the after-treatment systems, and more specifically the three-way catalysts. With recent developments in emission legislations, there is requirement for more complex after-treatment systems and understanding of the aging process. With future legislation introducing independent inspection of emissions at any time under real world driving conditions throughout a vehicle life cycle this is going to increase the focus on understanding catalyst behavior during any likely conditions throughout its lifetime and not just at the beginning and end. In recent years it has become a popular approach to use accelerated aging of the automotive catalysts for the development of new catalytic formulations and for homologation of new vehicle emissions.

A research project has been undertaken with the aim of characterizing and modeling the oxygen storage process in a three way automotive catalyst. The model consists of an oxygen storage sub-model and a kinetic reaction sub-model. Validation data for these models was recorded from a purpose-built catalyst flow reactor which uses O2 and NO as the oxidizing agents and CO, C3H6 and C3H8 as the reducing agents. The main focus of the work is the oxygen storage sub-model and the identification of the relevant constants for the reaction kinetic equations. The procedure used for measuring the oxygen storage capacity, and the oxygen storage and release rates from ceria (CeO2), is presented and discussed. The activation energies and activity factors for all the oxidation and reduction components were also found from the apparatus and used in the model.

With emission legislation becoming ever more stringent, automotive companies are forced to invest heavily into solutions to meet the targets set. To date the most effective way of treating emissions is through the use of catalytic converters. Current testing methods of catalytic converters whether being tested on a vehicle or in a lab reactor can be expensive and offer little information about what is occurring within the catalyst. It is for this reason and the increased price of precious metal that kinetic modeling has become a popular alternative to experimental testing. Many kinetic models and kinetic parameters have appeared in literature in recent years, a comparison of these kinetic parameters for the global reaction of CO oxidation is presented.

This paper describes the development and on-vehicle validation testing of next generation parallel hybrid electric powertrain technology for use in urban buses. A forward-facing MATLAB/Simulink powertrain model was used to develop a rule-based deterministic control system for a post-transmission parallel hybrid urban bus. The control strategy targeted areas where conventional powertrains are typically less efficient, focused on improving fuel economy and emissions without boosting vehicle performance. Stored electrical energy is deployed to assist the IC engine system leading to an overall reduction in fuel consumption while maintaining vehicle performance at a level comparable with baseline conventional IC engine operation.

With emission legislations becoming ever more stringent, there is an increased pressure on after-treatment systems and more specifically three-way catalysts. With recent developments in emission legislations, there is a requirement for more complex after-treatment systems and understanding of the aging process. Whilst the body of understanding on catalyst deactivation and, in particular, catalyst aging is growing, there are still significant gaps in understanding, particularly how real world variations in temperature, flow rate and gas concentrations affect catalyst behavior. Under normal driving conditions, the catalyst can experience varying oxygen concentrations, such as under heavy acceleration or cruising down a hill will show a variation in oxygen from the engine emissions. The effect that varying oxygen concentrations has on the rate of aging is not fully understood and hence the total deactivation and conversion efficiencies are not known throughout the catalyst lifetime.

The internal combustion (IC) engines exploits only about 30% of the chemical energy ejected through combustion, whereas the remaining part is rejected by means of cooling system and exhausted gas. Nowadays, a major global concern is finding sustainable solutions for better fuel economy which in turn results in a decrease of carbon dioxide (CO2) emissions. The Waste Heat Recovery (WHR) is one of the most promising techniques to increase the overall efficiency of a vehicle system, allowing the recovery of the heat rejected by the exhaust and cooling systems. In this context, Organic Rankine Cycles (ORCs) are widely recognized as a potential technology to exploit the heat rejected by engines to produce electricity. The aim of the present paper is to investigate a WHR system, designed to collect both coolant and exhausted gas heats, coupled with an ORC cycle for vehicle applications.

A Three-way automotive catalyst's ability to store oxygen is still a crucial performance metric for modern day catalyst applications. With more stringent emissions legalisation, the oxygen storage capacity (OSC) within the catalyst can assist with converting different exhaust gases such as CO, THC and NOx under transient operating conditions. OSC is currently the only onboard catalyst performance metric recorded during a vehicle's useful life. Catalyst performance is correlated to this OSC measurement. Rhodium is a precious metal used in automotive catalysts to help with the conversion of NOx. The price of rhodium is increasing drastically, requiring original equipment manufacturers (OEMs) to look at cost-effective alternatives to maintain NOx conversion within the exhaust stream. OSC in the catalyst is possible due to ceria in the washcoat. Stored oxygen can help promote other reactions in the catalyst bed to help with the conversion of NOx.