Technical Paper
The Effect of Di-Tertiary Butyl Peroxide (DTBP) Addition to Gasoline on HCCI Combustion
2003-10-27
2003-01-3170
A combination of engine experiments and modeling was used to investigate the effectiveness of adding di-tertiary butyl peroxide (DTBP) to gasoline to extend the light load limit in a homogeneous charge compression-ignition (HCCI) engine. The light load combustion stability limit at an engine speed of 1000 rev/min was reduced from a fueling rate of 9 mg/cycle with neat gasoline to 6.2 mg/cycle with 15% DTBP addition. A companion modeling study was performed using a three-zone, zero-dimensional engine model combined with detailed chemical kinetics. The fuel used in the model was composed of 85% iso-octane and 15% n-heptane. The model yielded trends which were similar to the experimental results. In particular, a linear relationship was found between the experimentally measured minimum fueling rate and the calculated location of maximum energy release rate for various levels of DTBP addition.