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Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.

Thermal effectiveness of Exhaust Gas Recirculation (EGR) coolers used in diesel engines can progressively decrease and stabilize over time due to inner fouling layer of the cooler tubes. Thermophoretic force has been identified as the major cause of diesel exhaust soot fouling, and models are proposed in the literature but improvements in simulation are needed especially for the long-term trend of soot deposition. To describe the fouling stabilization behavior, a removal mechanism is required to account for stabilization of the soot layer. Observations from previous experiments on surrogate circular tubes suggest there are three primary factors to determine removal mechanisms: surface temperature, thickness, and shear velocity. Based on this hypothesis, we developed a 1D CFD fouling model for predicting the thermal effectiveness reduction of real EGR coolers. The model includes the two competing mechanisms mentioned that results in fouling balance.

We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.

Projected NOx and fuel costs are compared for a plasma-catalyst system and an active lean NOx catalyst system. Comparisons are based on modeling of FTP cycle performance. The model uses steady state laboratory device characteristics, combined with measured vehicle exhaust data to predict NOx conversion efficiency and fuel economy penalties. The plasma system uses a proprietary catalyst downstream of a plasma discharge. The active lean NOx catalyst uses a catalyst along with addition of hydrocarbons to the exhaust. For the plasma catalyst system, NOx conversion is available over a wide temperature range. Increased electrical power improves conversion but degrades vehicle fuel economy; 10 J/L energy deposition costs roughly 3% fuel economy. Improved efficiency is also available with larger catalyst size or increased exhaust hydrocarbon content. For the active lean NOx system, NOx conversion is available only in a narrow temperature range.

Previously reported experiments revealed the presence of a small number of clusters or very small particles in the effluent of a nonthermal plasma reactor when treating a simulated engine exhaust mixture. These clusters are smaller than 7 nm. The quantity of clusters is orders of magnitude smaller than the particulate diesel or gasoline engine exhaust typically contains. In this report, we describe further experiments designed to determine the chemical composition of the clusters. Clusters were collected on the surface of a silicon substrate by exposing it to the effluent flow for extended time periods. The resulting deposits were analyzed by high mass resolution SIMS and by XPS. The SIMS analysis reveals NH4+, CH6N+, SO-, SO2-, SO3- and HSO4- ions. XPS reveals the presence of N and S at binding energies consistent with that of ammonium sulfate.

This paper describes the reduction of cyclic combustion variations in spark-ignited engines, especially under idle conditions in which the air-fuel mixture is lean of stoichiometry. Under such conditions, the combination of residual cylinder gas and parametric variations (such as variations in fuel preparation) gives rise to significant combustion instabilities that may lead to customer-perceived engine roughness and transient emissions spikes. Such combustion instabilities may preclude operation at air-fuel ratios that would otherwise be advantageous for fuel economy and emissions. This approach exploits the recognition that a component of the observed combustion instability results from a noise-driven, nonlinear deterministic mechanism that can be actively stabilized by small feedback control actions which result in little if any additional use of fuel.

The buildup of deposits in EGR coolers causes significant degradation in heat transfer performance, often on the order of 20-30%. Deposits also increase pressure drop across coolers and thus may degrade engine efficiency under some operating conditions. It is unlikely that EGR cooler deposits can be prevented from forming when soot and HC are present. The presence of cooled surfaces will cause thermophoretic soot deposition and condensation of HC and acids. While this can be affected by engine calibration, it probably cannot be eliminated as long as cooled EGR is required for emission control. It is generally felt that “dry fluffy” soot is less likely to cause major fouling than “heavy wet” soot. An oxidation catalyst in the EGR line can remove HC and has been shown to reduce fouling in some applications. The combination of an oxidation catalyst and a wall-flow filter largely eliminates fouling. Various EGR cooler designs affect details of deposit formation.

A diesel fuel and air diffusion flame burner system has been designed for laboratory simulation of diesel exhaust gas. The system consists of mass flow controllers and a fuel pump, and employs several unique design and construction features. It produces particulate emissions with size, number distribution, and morphology similar to diesel exhaust. At the same time, it generates NOx emissions and HC similar to diesel. The system has been applied to test plasma discharges. Different design discharge devices have been tested, with results indicating the importance of testing devices with soot and moisture. Both packed bed reactor and flat plate dielectric barrier discharge systems remove some soot from the gas, but the designs tested are susceptible to soot fouling and related electrical failures. The burner is simple and stable, and is suitable for development and aging of plasma and catalysts systems in the laboratory environment.

ERRATUM: In the article Reference 24 should read as follows: 24. Han, T., Booth, A., Song, S., Styles, D., and Hoard, J., “Review and A Conceptual Model of Exhaust Gas Recirculation (EGR) Cooler Fouling Deposition and Removal Mechanism” Proceedings of the Int. Conf. on Heat Exchanger Fouling and Cleaning, 2015”

A planar dielectric barrier discharge device has been tested for exhaust emission reduction in simulated engine exhaust. This device's electrical characteristics have been measured and are presented in this paper. The device consists of two dielectric barriers which act like series capacitors, with the gas gap between them. At low gap voltages, the gas gap also acts like a capacitance, with a much smaller capacitance than the barriers. At higher voltages, the gas gap breaks down and a blue–purple glow visually fills the gap. The partially ionized gas conducts charge across the gap, building electrical charge on the dielectric barrier inner surface. When the AC excitation voltage peaks and starts to go toward an opposite polarity, the discharge momentarily extinguishes, trapping charge in the dielectric barrier capacitance.

As European and Chinese tailpipe emission regulations for gasoline light-duty vehicles impose particulate number limits, automotive manufacturers have begun equipping some vehicles with a gasoline particulate filter (GPF). Increased understanding of how soot morphology, reactivity, and GPF loading affect GPF filtration and regeneration characteristics is necessary for advancing GPF performance. This study investigates the impacts of morphology, reactivity, and filter soot loading on GPF filtration and regeneration. Soot morphology and reactivity are varied through changes in fuel injection parameters, known to affect soot formation conditions. Changes in morphology and reactivity are confirmed through analysis using a transmission electron microscope (TEM) and a thermogravimetric analyzer (TGA) respectively.

Cooled EGR provides benefits in better fuel economy and lower emissions by reducing knocking tendency and decreasing peak cylinder temperature in gasoline engines. However, GDI engines have high particle emissions due to limited mixing of fuel and air, and these particle emissions can be a major source of EGR cooler fouling. In order to improve our knowledge of GDI engine EGR cooler fouling, the effects of tube geometry and coolant temperature on EGR cooler performance and degradation were studied using a four cylinder 2.0L turbocharged GDI engine. In addition, deposit microstructure was analyzed to explore the nature of deposits formed under GDI engine operation. The results of this study showed that a dented tube geometry was more effective in cooling the exhaust gas than a smooth tube due to its large surface area and turbulent fluid motion. However, more deposits were accumulated and higher effectiveness loss was observed in the dented tube.

Promising lean NOx trap (LNT) results on lean-burn gasoline engines have encouraged the development of LNTs for diesel applications. Although the fundamentals of LNT are common for both gasoline and diesel applications, there are major differences due to the character of engine operation and control strategies. The sulfur tolerance and thermal durability of current state-of-the-art diesel LNTs under the conditions that represent the thermal and chemical conditions in diesel exhaust were investigated in a laboratory flow reactor. Sulfur poisoning and thermal aging are unavoidable factors contributing to diesel LNT deactivation. The results show that sensitivity to sulfur poisoning varies with the catalyst formulations, and in some formulations the sulfur poisoning appears reversible. However, the thermal deactivation is permanent regardless of its cause, i.e., LNT de-sulfation (deSOx) or diesel particular filter (DPF) regeneration.

Compact heat exchangers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases, resulting in decreased NOx emissions. These exhaust gas recirculation (EGR) coolers experience fouling through deposition of particulate matter (PM) and hydrocarbons (HCs) that reduces the effectiveness of the cooler. Surrogate tubes have been used to investigate the impacts of gas flow rate and coolant temperature on the deposition of PM and HCs. The results indicate that mass deposition is lowest at high flow rates and high coolant temperatures. An oxidation catalyst was investigated and proved to effectively reduce deposition of HCs, but did not reduce overall mass deposition to near-zero levels. Speciation of the deposit HCs showed that a range of HCs from C15 - C25 were deposited and retained in the surrogate tubes.

The automotive industry has been witnessing a major shift towards downsized boosted direct injection engines due to diminishing petroleum reserves and increasingly stringent emission targets. Boosted engines operate at a high mean effective pressure (MEP), resulting in higher in-cylinder pressures and temperatures, effectively leading to increased possibility of abnormal combustion events like knock and pre-ignition. Therefore, the compression ratio and boost pressure in modern engines are restricted, which in-turn limits the engine efficiency and power. To mitigate conditions where the engine is prone to knocking, the engine control system uses spark retard and/or mixture enrichment, which decrease indicated work and increase specific fuel consumption. Several researchers have advocated water injection as an approach to replace or supplement existing knock mitigation techniques.

EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.

Ammonia, often present in exhaust gas samples, is a polar molecule gas that interacts with walls of the gas sampling and analysis equipment resulting in delayed instrument response. A set of experiments quantified various materials and process parameters of a heated sample line system for ammonia (NH3) response using a Fourier Transform infrared spectrometer (FTIR). Response attenuation rates are due to mixing and diffusion during transport as well as NH3 wall storage. Mixing/diffusion effects cause attenuation with a time constant 1-10 seconds. Wall storage attenuation has a time constant 10-200 seconds. The effects of sample line diameter and length, line temperature, line material, hydrated versus dry gas, and flow rate were examined. All of these factors are statistically significant to variation of at least one of the time constants. The NH3 storage on the sample system walls was calculated as a function of the experimental test as well.

NOx reduction efficiency under simulated lean burn conditions is examined for a non-thermal plasma in combination with borosilicate glass, alumina, titania, Cu-ZSM-5 and Na-ZSM-5. The non-thermal plasma alone or with a packed bed of borosilicate glass beads converts NO to NO2 and partially oxidizes hydrocarbons. Alumina and Na-ZSM-5 reduce a maximum of 40% and 50% of NOx respectively; however, the energy cost is high for Na- ZSM-5. Cu-ZSM-5 converts less than 20% with a very high energy consumption. The anatase form of titania reduces up to 35% of NOx at a relatively high energy consumption (150J/L) when the catalyst is contained in the plasma region, but does not show any appreciable conversion when placed downstream from the reactor. This phenomenon is explained by photo-activation of anatase in the plasma.

Modern diesel aftertreatment systems may produce ammonia (NH3), especially in gas samples from midbed locations. NH3 causes significant measurement errors in NO, NO2, and NOx measurements for several NOx measurement technologies. A standard addition test was run adding NO, NO2, and/or NH3 to a diesel engine exhaust. Chemiluminescent (CLD), FTIR, and chemical ionization mass spectrometer (CIMS) instruments were used in a designed experiment. None of the instruments gave accurate, robust NOx measurement in the presence of high levels of NH3.

There is a need for an efficient, durable technology to reduce NOx emissions from oxidative exhaust streams such as those produced by compression-ignition, direct-injection (CIDI) diesel or lean-burn gasoline engines. A partnership formed between the DOE Office of Advanced Automotive Technology, Pacific Northwest National Laboratory, Oak Ridge National Laboratory and the USCAR Low Emission Technologies Research and Development Partnership is evaluating the effectiveness of a non-thermal plasma in conjunction with catalytic materials to mediate NOx and particulate emissions from diesel fueled light duty (CIDI) engines. Preliminary studies showed that plasma-catalyst systems could reduce up to 70% of NOx emissions at an equivalent cost of 3.5% of the input fuel in simulated diesel exhaust. These studies also showed that the type and concentration of hydrocarbon play a key role in both the plasma gas phase chemistry and the catalyst surface chemistry.